FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024748594> ?p ?o ?g. }

• W2024748594 endingPage "3280" @default.
• W2024748594 startingPage "3275" @default.
• W2024748594 abstract "Triphenylphosphinecobaloxime(II) has been found to be a selective catalyst for the oxidative dehydrogenation of 3,5-di-tert-butylcatechol to the corresponding 1,2-benzoquinone at room temperature and atmospheric dioxygen pressure. In a rapid initial phase the catalyst is reversibly transformed to a previously characterised catecholatocobaloxime(III) species, which persists throughout the reaction, keeping CoII at a low level. The semiquinone anion radical (dbsq˙–) and its cobaloxime(III) complex CoIII(dbsq˙–) have been detected as intermediates by ESR spectroscopy. The kinetics was followed by volumetry. According to the proposed mechanism, in the rate-determining step superoxocobaloxime (CoIIIO2) abstracts an H atom from the cathechol via an hydrogen-bonded intermediate. The system investigated is a functional model of catecholase (oxidase) activity, based on free-radical intermediates, a possibility recently demonstrated for certain oxidoreductases." @default.
• W2024748594 created "2016-06-24" @default.
• W2024748594 creator A5024254961 @default.
• W2024748594 creator A5047097144 @default.
• W2024748594 date "1998-01-01" @default.
• W2024748594 modified "2023-10-18" @default.
• W2024748594 title "Kinetics and mechanism of the cobaloxime(II)-catalysed oxidative dehydrogenation of 3,5-di-tert-butylcatechol by O2. A functional oxidase model" @default.
• W2024748594 cites W14652194 @default.
• W2024748594 cites W1966114000 @default.
• W2024748594 cites W1969522337 @default.
• W2024748594 cites W1983559510 @default.
• W2024748594 cites W1988603777 @default.
• W2024748594 cites W1992750628 @default.
• W2024748594 cites W1996096107 @default.
• W2024748594 cites W1997265177 @default.
• W2024748594 cites W2003987609 @default.
• W2024748594 cites W2009580317 @default.
• W2024748594 cites W2011450394 @default.
• W2024748594 cites W2019272015 @default.
• W2024748594 cites W2020336471 @default.
• W2024748594 cites W2020712393 @default.
• W2024748594 cites W2029459898 @default.
• W2024748594 cites W2052743745 @default.
• W2024748594 cites W2064365288 @default.
• W2024748594 cites W2080136555 @default.
• W2024748594 cites W2087985412 @default.
• W2024748594 cites W2088505263 @default.
• W2024748594 cites W2089546734 @default.
• W2024748594 cites W2091936048 @default.
• W2024748594 cites W2091960606 @default.
• W2024748594 cites W2951619989 @default.
• W2024748594 cites W3082433430 @default.
• W2024748594 doi "https://doi.org/10.1039/a803597k" @default.
• W2024748594 hasPublicationYear "1998" @default.
• W2024748594 type Work @default.
• W2024748594 sameAs 2024748594 @default.
• W2024748594 citedByCount "42" @default.
• W2024748594 countsByYear W20247485942013 @default.
• W2024748594 countsByYear W20247485942014 @default.
• W2024748594 countsByYear W20247485942015 @default.
• W2024748594 countsByYear W20247485942016 @default.
• W2024748594 countsByYear W20247485942018 @default.
• W2024748594 countsByYear W20247485942019 @default.
• W2024748594 countsByYear W20247485942020 @default.
• W2024748594 countsByYear W20247485942022 @default.
• W2024748594 countsByYear W20247485942023 @default.
• W2024748594 crossrefType "journal-article" @default.
• W2024748594 hasAuthorship W2024748594A5024254961 @default.
• W2024748594 hasAuthorship W2024748594A5047097144 @default.
• W2024748594 hasConcept C119889771 @default.
• W2024748594 hasConcept C121332964 @default.
• W2024748594 hasConcept C139066938 @default.
• W2024748594 hasConcept C148898269 @default.
• W2024748594 hasConcept C155647269 @default.
• W2024748594 hasConcept C161790260 @default.
• W2024748594 hasConcept C178790620 @default.
• W2024748594 hasConcept C185592680 @default.
• W2024748594 hasConcept C2776370595 @default.
• W2024748594 hasConcept C2776640939 @default.
• W2024748594 hasConcept C2779686393 @default.
• W2024748594 hasConcept C2780263894 @default.
• W2024748594 hasConcept C2780643102 @default.
• W2024748594 hasConcept C55493867 @default.
• W2024748594 hasConcept C57600042 @default.
• W2024748594 hasConcept C62520636 @default.
• W2024748594 hasConcept C63338738 @default.
• W2024748594 hasConcept C65024703 @default.
• W2024748594 hasConcept C71240020 @default.
• W2024748594 hasConcept C75473681 @default.
• W2024748594 hasConceptScore W2024748594C119889771 @default.
• W2024748594 hasConceptScore W2024748594C121332964 @default.
• W2024748594 hasConceptScore W2024748594C139066938 @default.
• W2024748594 hasConceptScore W2024748594C148898269 @default.
• W2024748594 hasConceptScore W2024748594C155647269 @default.
• W2024748594 hasConceptScore W2024748594C161790260 @default.
• W2024748594 hasConceptScore W2024748594C178790620 @default.
• W2024748594 hasConceptScore W2024748594C185592680 @default.
• W2024748594 hasConceptScore W2024748594C2776370595 @default.
• W2024748594 hasConceptScore W2024748594C2776640939 @default.
• W2024748594 hasConceptScore W2024748594C2779686393 @default.
• W2024748594 hasConceptScore W2024748594C2780263894 @default.
• W2024748594 hasConceptScore W2024748594C2780643102 @default.
• W2024748594 hasConceptScore W2024748594C55493867 @default.
• W2024748594 hasConceptScore W2024748594C57600042 @default.
• W2024748594 hasConceptScore W2024748594C62520636 @default.
• W2024748594 hasConceptScore W2024748594C63338738 @default.
• W2024748594 hasConceptScore W2024748594C65024703 @default.
• W2024748594 hasConceptScore W2024748594C71240020 @default.
• W2024748594 hasConceptScore W2024748594C75473681 @default.
• W2024748594 hasIssue "19" @default.
• W2024748594 hasLocation W20247485941 @default.
• W2024748594 hasOpenAccess W2024748594 @default.
• W2024748594 hasPrimaryLocation W20247485941 @default.
• W2024748594 hasRelatedWork W2006549952 @default.
• W2024748594 hasRelatedWork W2028931691 @default.
• W2024748594 hasRelatedWork W2033308226 @default.
• W2024748594 hasRelatedWork W2041341901 @default.
• W2024748594 hasRelatedWork W2053772394 @default.

• next