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• W2024749585 startingPage "6406" @default.
• W2024749585 abstract "Electron and energy transfer from copper 1,10-phenanthroline excited states is observed at room temperature in organic solvents. The copper phenanthroline excited states are metal-to-ligand charge-transfer in nature and have lifetimes of approximately 70-250 ns in dichloromethane solution if methyl or phenyl substituents are placed in the 2- and 9-positions of the phenanthroline ligand. The unsubstituted cuprous compound Cu(phen)(2)(PF(6)) is nonemissive under these conditions, and the excited state lifetime is <20 ns. The rate and efficiency of energy transfer to anthracene or electron transfer to viologens is reported. The cage escape efficiency of [Cu(dpp)(2)(2+), MV(+)(*)], where dpp is 2,9-diphenyl-1,10-phenanthroline, is close to unity within experimental error. Back electron transfer to ground state products occurs at the diffusion limit, 2 x 10(10) M(-)(1) s(-)(1)." @default.
• W2024749585 created "2016-06-24" @default.
• W2024749585 creator A5017888744 @default.
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• W2024749585 date "1996-01-01" @default.
• W2024749585 modified "2023-10-16" @default.
• W2024749585 title "Photodriven Electron and Energy Transfer from Copper Phenanthroline Excited States" @default.
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• W2024749585 doi "https://doi.org/10.1021/ic960503z" @default.
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