Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024750692> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W2024750692 endingPage "2530" @default.
- W2024750692 startingPage "2527" @default.
- W2024750692 abstract "Photochemical and Thermal Generation of Thiocarbonyl Ylides from 2,5-Dihydro-1,3,4-thiadiazoles[*] Thermolysis of thiadiazolines 2a-c yields the corresponding thiiranes 5a-c exclusively. In contrast matrix photolysis in an organic glass at 77 K or in solid Ar at 10 K allows the detection of the thiocarbonyl ylides 3a-c, which are characterized by intense UV maxima at λ ≈ 350 nm. The thiocarbonyl ylides are formed in a stepwise manner and not directly from the thiadiazolines by a simple elimination of N2. In the first step a fragmentation into the thioketones 6a-c and diazomethane occurs, followed by the generation of methylene (8) from diazomethane (7). Addition of methylene to the thioketones 6a-c finally leads to the ylides 3a-c." @default.
- W2024750692 created "2016-06-24" @default.
- W2024750692 creator A5010034962 @default.
- W2024750692 creator A5011321491 @default.
- W2024750692 creator A5022355782 @default.
- W2024750692 creator A5044271806 @default.
- W2024750692 creator A5088120245 @default.
- W2024750692 date "1994-12-01" @default.
- W2024750692 modified "2023-10-09" @default.
- W2024750692 title "Photochemische und thermische Erzeugung von Thiocarbonylyliden aus 2,5‐Dihydro‐1,3,4‐thiadiazolen" @default.
- W2024750692 cites W1964492585 @default.
- W2024750692 cites W1994803495 @default.
- W2024750692 cites W1996212147 @default.
- W2024750692 cites W1998216479 @default.
- W2024750692 cites W2015123274 @default.
- W2024750692 cites W2018703384 @default.
- W2024750692 cites W2020239133 @default.
- W2024750692 cites W2024469640 @default.
- W2024750692 cites W2038140519 @default.
- W2024750692 cites W2039760333 @default.
- W2024750692 cites W2049323109 @default.
- W2024750692 cites W2052262014 @default.
- W2024750692 cites W2088810617 @default.
- W2024750692 cites W2089800316 @default.
- W2024750692 cites W2094143710 @default.
- W2024750692 cites W2111791553 @default.
- W2024750692 cites W2123249458 @default.
- W2024750692 cites W2333315766 @default.
- W2024750692 cites W2951076760 @default.
- W2024750692 cites W2952251850 @default.
- W2024750692 cites W3005488042 @default.
- W2024750692 cites W4242683902 @default.
- W2024750692 doi "https://doi.org/10.1002/cber.19941271226" @default.
- W2024750692 hasPublicationYear "1994" @default.
- W2024750692 type Work @default.
- W2024750692 sameAs 2024750692 @default.
- W2024750692 citedByCount "23" @default.
- W2024750692 countsByYear W20247506922012 @default.
- W2024750692 countsByYear W20247506922016 @default.
- W2024750692 countsByYear W20247506922020 @default.
- W2024750692 countsByYear W20247506922021 @default.
- W2024750692 crossrefType "journal-article" @default.
- W2024750692 hasAuthorship W2024750692A5010034962 @default.
- W2024750692 hasAuthorship W2024750692A5011321491 @default.
- W2024750692 hasAuthorship W2024750692A5022355782 @default.
- W2024750692 hasAuthorship W2024750692A5044271806 @default.
- W2024750692 hasAuthorship W2024750692A5088120245 @default.
- W2024750692 hasConcept C111919701 @default.
- W2024750692 hasConcept C124681953 @default.
- W2024750692 hasConcept C155647269 @default.
- W2024750692 hasConcept C160434732 @default.
- W2024750692 hasConcept C178790620 @default.
- W2024750692 hasConcept C185592680 @default.
- W2024750692 hasConcept C191015642 @default.
- W2024750692 hasConcept C2777454769 @default.
- W2024750692 hasConcept C2779167645 @default.
- W2024750692 hasConcept C2780374730 @default.
- W2024750692 hasConcept C41008148 @default.
- W2024750692 hasConcept C54582936 @default.
- W2024750692 hasConcept C75473681 @default.
- W2024750692 hasConceptScore W2024750692C111919701 @default.
- W2024750692 hasConceptScore W2024750692C124681953 @default.
- W2024750692 hasConceptScore W2024750692C155647269 @default.
- W2024750692 hasConceptScore W2024750692C160434732 @default.
- W2024750692 hasConceptScore W2024750692C178790620 @default.
- W2024750692 hasConceptScore W2024750692C185592680 @default.
- W2024750692 hasConceptScore W2024750692C191015642 @default.
- W2024750692 hasConceptScore W2024750692C2777454769 @default.
- W2024750692 hasConceptScore W2024750692C2779167645 @default.
- W2024750692 hasConceptScore W2024750692C2780374730 @default.
- W2024750692 hasConceptScore W2024750692C41008148 @default.
- W2024750692 hasConceptScore W2024750692C54582936 @default.
- W2024750692 hasConceptScore W2024750692C75473681 @default.
- W2024750692 hasIssue "12" @default.
- W2024750692 hasLocation W20247506921 @default.
- W2024750692 hasOpenAccess W2024750692 @default.
- W2024750692 hasPrimaryLocation W20247506921 @default.
- W2024750692 hasRelatedWork W2002279218 @default.
- W2024750692 hasRelatedWork W2003637121 @default.
- W2024750692 hasRelatedWork W2018700061 @default.
- W2024750692 hasRelatedWork W2051099519 @default.
- W2024750692 hasRelatedWork W2061061222 @default.
- W2024750692 hasRelatedWork W2070031917 @default.
- W2024750692 hasRelatedWork W2079679085 @default.
- W2024750692 hasRelatedWork W2090507350 @default.
- W2024750692 hasRelatedWork W2170677868 @default.
- W2024750692 hasRelatedWork W2952641847 @default.
- W2024750692 hasVolume "127" @default.
- W2024750692 isParatext "false" @default.
- W2024750692 isRetracted "false" @default.
- W2024750692 magId "2024750692" @default.
- W2024750692 workType "article" @default.