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- W2024761397 abstract ". A novel 1D PbII coordination polymer [Pb(dmp)I2]n (1) (dmp = 2,9-dimethyl-1,10-phenanthroline) containing a Pb2-(μ-I)2 unit was synthesized and characterized by elemental analysis, IR, 1H NMR, and 13C NMR spectroscopy and studied by thermal analysis as well as X-ray crystallography. The single-crystal X-ray data show that the coordination number of PbII ions is six, i.e. PbN2I4, with “stereo-chemically active” electron lone pairs, and the coordination sphere is asymmetrical. They also show that the chains interact with each other through π-π stacking interactions, which create a 3D framework. The structure of the title complex has been optimized by density functional theory calculations. The calculated structural parameters and the IR spectra of the title complex are in agreement with the crystal structure." @default.
- W2024761397 created "2016-06-24" @default.
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- W2024761397 date "2010-03-08" @default.
- W2024761397 modified "2023-09-24" @default.
- W2024761397 title "A Novel Metal-Ligand Iodo-bridged Lead(II) Compound: Synthesis, Crystal Structure, Thermal Properties, and DFT Calculations of [Pb(dmp)I2]n" @default.
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- W2024761397 doi "https://doi.org/10.1002/zaac.200900511" @default.
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