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• W2024762679 abstract "By means of mass spectrometric experiments, a semi-quantitative potential-energy surface for the coupled CO and CH bond activation of dimethylether by gaseous Fe+ is proposed, which can account for all experimental observations made for this system. Thus, the insertion of the metal cation into the CO bond to afford the insertion species [CH3–Fe–OCH3]+ is rate determining, followed by β-hydrogen transfer to first afford the bisligated complex (CH4)Fe(CH2O)+ and then the final products Fe(CH2O)+ + CH4." @default.
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• W2024762679 date "2006-09-01" @default.
• W2024762679 modified "2023-10-14" @default.
• W2024762679 title "An experimental study of the mechanism for the combined CO and CH bond activation of dimethylether by bare Fe+ ions" @default.
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• W2024762679 doi "https://doi.org/10.1016/j.ijms.2005.12.030" @default.
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