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• W2024765367 abstract "Measurement of the specific conductance, pH, and zeta potential of latex dispersions upon titration with acid or base have been used by several workers to determine the number and nature of the surface ionizable groups. The ionization of latexes with single or several types of surface groups is modified by the interaction of the surface charge and potential with solute ions and is often complex and difficult to interpret in a quantitative manner. The solution of this problem requires (a) accurate estimates of the chemical and surface parameters of the particular latex dispersion, and (b) a reliable model for the potential and charge distribution at the latex/water interface. We describe the results of calculations using a general computer program for solving complex solution and surface reaction equilibria. The surface ion binding of electrolytes is shown to be a major contributing reaction for surface charge development and a new double extrapolation method for determining the intrinsic equilibrium constants for simple ionization and complex ionization reactions is outlined. Simulated titrations in which pH, specific conductivity, κ, and zeta potential, ζ, are estimated for each addition of base or acid are given and compared to reported results." @default.
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• W2024765367 date "1978-06-01" @default.
• W2024765367 modified "2023-09-26" @default.
• W2024765367 title "Computer simulation of the conductometric and potentiometric titrations of the surface groups on ionizable latexes" @default.
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• W2024765367 doi "https://doi.org/10.1016/0021-9797(78)90164-9" @default.
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