Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024772571> ?p ?o ?g. }
- W2024772571 endingPage "794" @default.
- W2024772571 startingPage "777" @default.
- W2024772571 abstract "The reaction of methyl radicals with atomic and molecular oxygen was studied with a photoionization mass spectrometer. The methyl radicals were generated by reacting oxygen atoms with ethylene in a fast-flow tube reactor. The rate constant for the reaction of methyl radicals with oxygen atoms was (1.0 ± 0.2) × 10−10 cm3/molec · sec with no significant variation with temperature over the range of 259–341°K. The reaction of methyl radicals with molecular oxygen involves both a two-body reaction, having a rate constant documentclass{article}pagestyle{empty}begin{document}$begin{array}{*{20}c} {k_{{rm 3a}} = (10^{- 12.54 pm 0.35})exp [(- 940 pm 250)T^{- 1}]} & {{rm cm}^{rm 3} /{rm molec} cdot {rm sec}} end{array}$end{document} and a three-body recombination having a negative temperature dependence. The methyl peroxy radical could be observed at its steady-state concentration. The rate constants determined at low pressures are compatible with the values determined at higher pressures by flash photolysis. Formaldehyde appears to be a major product of the two-body reaction of CH3 with O2, and also of the reaction of CH3O2 with oxygen atoms." @default.
- W2024772571 created "2016-06-24" @default.
- W2024772571 creator A5049634006 @default.
- W2024772571 creator A5072130778 @default.
- W2024772571 date "1976-09-01" @default.
- W2024772571 modified "2023-09-25" @default.
- W2024772571 title "The reactions of methyl radicals with atomic and molecular oxygen" @default.
- W2024772571 cites W1956286340 @default.
- W2024772571 cites W1967908778 @default.
- W2024772571 cites W1972189790 @default.
- W2024772571 cites W1979865352 @default.
- W2024772571 cites W1981849257 @default.
- W2024772571 cites W1984134573 @default.
- W2024772571 cites W1985065027 @default.
- W2024772571 cites W1986891015 @default.
- W2024772571 cites W2008683983 @default.
- W2024772571 cites W2009456992 @default.
- W2024772571 cites W2015239970 @default.
- W2024772571 cites W2016837320 @default.
- W2024772571 cites W2037377547 @default.
- W2024772571 cites W2042603395 @default.
- W2024772571 cites W2047501869 @default.
- W2024772571 cites W2060555179 @default.
- W2024772571 cites W2078506462 @default.
- W2024772571 cites W2079643486 @default.
- W2024772571 cites W2082748645 @default.
- W2024772571 cites W2083620711 @default.
- W2024772571 cites W2089034458 @default.
- W2024772571 cites W2099599050 @default.
- W2024772571 cites W2106646821 @default.
- W2024772571 cites W2314105390 @default.
- W2024772571 cites W2324026910 @default.
- W2024772571 cites W2368595962 @default.
- W2024772571 doi "https://doi.org/10.1002/kin.550080512" @default.
- W2024772571 hasPublicationYear "1976" @default.
- W2024772571 type Work @default.
- W2024772571 sameAs 2024772571 @default.
- W2024772571 citedByCount "59" @default.
- W2024772571 countsByYear W20247725712016 @default.
- W2024772571 countsByYear W20247725712019 @default.
- W2024772571 countsByYear W20247725712020 @default.
- W2024772571 countsByYear W20247725712022 @default.
- W2024772571 countsByYear W20247725712023 @default.
- W2024772571 crossrefType "journal-article" @default.
- W2024772571 hasAuthorship W2024772571A5049634006 @default.
- W2024772571 hasAuthorship W2024772571A5072130778 @default.
- W2024772571 hasConcept C113196181 @default.
- W2024772571 hasConcept C121332964 @default.
- W2024772571 hasConcept C13472781 @default.
- W2024772571 hasConcept C139066938 @default.
- W2024772571 hasConcept C145148216 @default.
- W2024772571 hasConcept C147789679 @default.
- W2024772571 hasConcept C148898269 @default.
- W2024772571 hasConcept C158749347 @default.
- W2024772571 hasConcept C162356407 @default.
- W2024772571 hasConcept C178790620 @default.
- W2024772571 hasConcept C185592680 @default.
- W2024772571 hasConcept C198291218 @default.
- W2024772571 hasConcept C2992086430 @default.
- W2024772571 hasConcept C39353612 @default.
- W2024772571 hasConcept C43617362 @default.
- W2024772571 hasConcept C540031477 @default.
- W2024772571 hasConcept C54582936 @default.
- W2024772571 hasConcept C62520636 @default.
- W2024772571 hasConcept C75473681 @default.
- W2024772571 hasConcept C93391505 @default.
- W2024772571 hasConcept C97355855 @default.
- W2024772571 hasConceptScore W2024772571C113196181 @default.
- W2024772571 hasConceptScore W2024772571C121332964 @default.
- W2024772571 hasConceptScore W2024772571C13472781 @default.
- W2024772571 hasConceptScore W2024772571C139066938 @default.
- W2024772571 hasConceptScore W2024772571C145148216 @default.
- W2024772571 hasConceptScore W2024772571C147789679 @default.
- W2024772571 hasConceptScore W2024772571C148898269 @default.
- W2024772571 hasConceptScore W2024772571C158749347 @default.
- W2024772571 hasConceptScore W2024772571C162356407 @default.
- W2024772571 hasConceptScore W2024772571C178790620 @default.
- W2024772571 hasConceptScore W2024772571C185592680 @default.
- W2024772571 hasConceptScore W2024772571C198291218 @default.
- W2024772571 hasConceptScore W2024772571C2992086430 @default.
- W2024772571 hasConceptScore W2024772571C39353612 @default.
- W2024772571 hasConceptScore W2024772571C43617362 @default.
- W2024772571 hasConceptScore W2024772571C540031477 @default.
- W2024772571 hasConceptScore W2024772571C54582936 @default.
- W2024772571 hasConceptScore W2024772571C62520636 @default.
- W2024772571 hasConceptScore W2024772571C75473681 @default.
- W2024772571 hasConceptScore W2024772571C93391505 @default.
- W2024772571 hasConceptScore W2024772571C97355855 @default.
- W2024772571 hasIssue "5" @default.
- W2024772571 hasLocation W20247725711 @default.
- W2024772571 hasOpenAccess W2024772571 @default.
- W2024772571 hasPrimaryLocation W20247725711 @default.
- W2024772571 hasRelatedWork W1162079594 @default.
- W2024772571 hasRelatedWork W2005696681 @default.
- W2024772571 hasRelatedWork W2024452683 @default.
- W2024772571 hasRelatedWork W2035626804 @default.
- W2024772571 hasRelatedWork W2069088477 @default.
- W2024772571 hasRelatedWork W2081434063 @default.