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- W2024779901 abstract "[reaction: see text] A novel total synthesis of 3',5'-C-branched uridine azido acid has been accomplished using stereoselective aldehyde alkynylation, Ireland-Claisen rearrangement, and iodolactonization as the key reactions. Compared to traditional routes that start from carbohydrates, the present methodology is more efficient, flexible for future optimization, and provides access to both enantiomers of the products. Because the key chemistry does not involve the 3'- and 5'-C substituents, our route is a general approach to 3',5'-C alkyl nucleoside analogues." @default.
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- W2024779901 date "2003-09-19" @default.
- W2024779901 modified "2023-09-24" @default.
- W2024779901 title "Total Synthesis of 3‘,5‘-C-Branched Nucleosides" @default.
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- W2024779901 doi "https://doi.org/10.1021/ol035619v" @default.
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