FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024780757> ?p ?o ?g. }

• W2024780757 endingPage "2539" @default.
• W2024780757 startingPage "2535" @default.
• W2024780757 abstract "By refluxing a mixture of (S)-α-methyl-4-nitrobenzylamine and Pd(O2CMe)2(1 : 1) in acetone, complexes (S,S)-[{Pd[C6H3{CH(Me)NH2}-2-NO2-5](µ-X)}2](X = MeCO21a or Cl 1b) are obtained. Complex 1b can also be obtained by treating (S)-α-methyl-4-nitrobenzylamine hydrochloride with Pd(O2CMe)2(1 : 1) in acetone. These complexes are the first orthometallated complexes containing a primary amine with an electron-withdrawing group in the benzene ring. Complex 1a reacted with an excess of NaBr or Nal to give (S,S)-[{Pd[C6H3{CH(Me)NH2}-2-NO2-5](µ-X)}2](X = Br 1c or I 1d). Triphenylphosphine reacted with 1b or 1c to give (S)-[Pd{C6H3[CH(Me)NH2]-2-NO2-5}X(PPH3)](X = Cl 2a or Br 2b). The reaction of complex 1b with AgClO4(1 : 1) and an excess of pyridine (py) gave (S)-[Pd{C6H3[CH(Me)NH2]-2-NO2-5}(py)2]ClO43. Complex 1c reacted with 3 equivalents of RCCR (R = CO2Me) to give a tri-insertion reaction product, the crystal structure of which has been determined: space group P212121, a= 11.0969(14), b= 17.197(2), c= 19.604(3)Å, R(F)= 0.041. The planar co-ordination at palladium is not significantly disturbed by a short contact of 2.600 Å to the C atom of a CO2Me group. A cationic derivative of this complex has also been prepared." @default.
• W2024780757 created "2016-06-24" @default.
• W2024780757 creator A5028694539 @default.
• W2024780757 creator A5047953018 @default.
• W2024780757 creator A5077854738 @default.
• W2024780757 creator A5089476171 @default.
• W2024780757 date "1995-01-01" @default.
• W2024780757 modified "2023-09-27" @default.
• W2024780757 title "The first orthopalladation of a primary nitrobenzylamine. Synthesis of chiral cyclopalladated complexes derived from (S)-α-methyl-4-nitrobenzylamine" @default.
• W2024780757 cites W1482601653 @default.
• W2024780757 cites W1498763929 @default.
• W2024780757 cites W1981264467 @default.
• W2024780757 cites W1985450285 @default.
• W2024780757 cites W1987958304 @default.
• W2024780757 cites W1998722626 @default.
• W2024780757 cites W2004561964 @default.
• W2024780757 cites W2010231909 @default.
• W2024780757 cites W2010691897 @default.
• W2024780757 cites W2016281653 @default.
• W2024780757 cites W2033068961 @default.
• W2024780757 cites W2035600458 @default.
• W2024780757 cites W2037048025 @default.
• W2024780757 cites W2050685374 @default.
• W2024780757 cites W2052967824 @default.
• W2024780757 cites W2062477343 @default.
• W2024780757 cites W2062767043 @default.
• W2024780757 cites W2063843847 @default.
• W2024780757 cites W2069899824 @default.
• W2024780757 cites W2073170027 @default.
• W2024780757 cites W2077750577 @default.
• W2024780757 cites W2086047594 @default.
• W2024780757 cites W2087106716 @default.
• W2024780757 cites W2089706849 @default.
• W2024780757 cites W2091206215 @default.
• W2024780757 cites W2117388430 @default.
• W2024780757 cites W2130649363 @default.
• W2024780757 cites W2142849525 @default.
• W2024780757 cites W2950854357 @default.
• W2024780757 cites W2951150634 @default.
• W2024780757 cites W2952141779 @default.
• W2024780757 cites W3139461015 @default.
• W2024780757 doi "https://doi.org/10.1039/dt9950002535" @default.
• W2024780757 hasPublicationYear "1995" @default.
• W2024780757 type Work @default.
• W2024780757 sameAs 2024780757 @default.
• W2024780757 citedByCount "55" @default.
• W2024780757 countsByYear W20247807572012 @default.
• W2024780757 countsByYear W20247807572013 @default.
• W2024780757 countsByYear W20247807572014 @default.
• W2024780757 countsByYear W20247807572016 @default.
• W2024780757 countsByYear W20247807572017 @default.
• W2024780757 countsByYear W20247807572021 @default.
• W2024780757 countsByYear W20247807572022 @default.
• W2024780757 crossrefType "journal-article" @default.
• W2024780757 hasAuthorship W2024780757A5028694539 @default.
• W2024780757 hasAuthorship W2024780757A5047953018 @default.
• W2024780757 hasAuthorship W2024780757A5077854738 @default.
• W2024780757 hasAuthorship W2024780757A5089476171 @default.
• W2024780757 hasConcept C106159729 @default.
• W2024780757 hasConcept C111771559 @default.
• W2024780757 hasConcept C115624301 @default.
• W2024780757 hasConcept C131779359 @default.
• W2024780757 hasConcept C155647269 @default.
• W2024780757 hasConcept C161790260 @default.
• W2024780757 hasConcept C162324750 @default.
• W2024780757 hasConcept C178790620 @default.
• W2024780757 hasConcept C183882617 @default.
• W2024780757 hasConcept C185592680 @default.
• W2024780757 hasConcept C188027245 @default.
• W2024780757 hasConcept C2777247709 @default.
• W2024780757 hasConcept C2777691172 @default.
• W2024780757 hasConcept C2779485729 @default.
• W2024780757 hasConcept C2780378348 @default.
• W2024780757 hasConcept C2781213060 @default.
• W2024780757 hasConcept C2781283055 @default.
• W2024780757 hasConcept C502130503 @default.
• W2024780757 hasConcept C71240020 @default.
• W2024780757 hasConcept C8010536 @default.
• W2024780757 hasConceptScore W2024780757C106159729 @default.
• W2024780757 hasConceptScore W2024780757C111771559 @default.
• W2024780757 hasConceptScore W2024780757C115624301 @default.
• W2024780757 hasConceptScore W2024780757C131779359 @default.
• W2024780757 hasConceptScore W2024780757C155647269 @default.
• W2024780757 hasConceptScore W2024780757C161790260 @default.
• W2024780757 hasConceptScore W2024780757C162324750 @default.
• W2024780757 hasConceptScore W2024780757C178790620 @default.
• W2024780757 hasConceptScore W2024780757C183882617 @default.
• W2024780757 hasConceptScore W2024780757C185592680 @default.
• W2024780757 hasConceptScore W2024780757C188027245 @default.
• W2024780757 hasConceptScore W2024780757C2777247709 @default.
• W2024780757 hasConceptScore W2024780757C2777691172 @default.
• W2024780757 hasConceptScore W2024780757C2779485729 @default.
• W2024780757 hasConceptScore W2024780757C2780378348 @default.
• W2024780757 hasConceptScore W2024780757C2781213060 @default.
• W2024780757 hasConceptScore W2024780757C2781283055 @default.
• W2024780757 hasConceptScore W2024780757C502130503 @default.
• W2024780757 hasConceptScore W2024780757C71240020 @default.
• W2024780757 hasConceptScore W2024780757C8010536 @default.

• next