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- W2024785549 abstract "Valence-band ultraviolet photoemission spectra of undoped poly(methylthiophene) show an extended $ensuremath{pi}$ bonding at 1.05 eV from the Fermi level, ${E}_{F}$. Doping with Cl${mathrm{O}}_{4}^{ensuremath{-}}$ proceeds through uniform extraction of $ensuremath{pi}$-bonding electrons resulting in (i) an extension of the $ensuremath{pi}$ band and (ii) an ${E}_{F}$ shift by 0.8 eV relative to this band and 0.5 eV relative to the core levels. Band-gap narrowing reduces the $ensuremath{pi}ensuremath{rightarrow}{ensuremath{pi}}^{*}$ shakeup energy of the x-ray photoemission spectroscopy Cl$s$ peak from 2.7 to 1.7 eV with a strong intensity enhancement." @default.
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- W2024785549 date "1986-04-28" @default.
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- W2024785549 title "Evidence of Intrinsic Extended<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>π</mml:mi></mml:math>-Bonding Band and Metalliclike Behavior in Undoped and Doped Electropolymerized Poly (3-methylthiophene) Films" @default.
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- W2024785549 doi "https://doi.org/10.1103/physrevlett.56.1862" @default.
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