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• W2024788823 abstract "The solubility behaviour of a polyoxyalkylene block co-polymer surfactant, known as poloxamer F-127, in liquid ethanol/CO 2 solvent mixtures at P = 10 MPa and T = 298 K, has been determined. Such a polymer presents a solubility in ethanol/CO 2 mixtures that is one or two orders of magnitude larger than in both pure liquids. This synergistic behaviour of ethanol and liquid CO 2 to solubilize the poloxamer F-127 has permitted the obtaining of solid particles of the poloxamer suspended in ethanol by depressurising its solutions in liquid ethanol/CO 2 mixtures, since the polymer is almost insoluble in the resulting ethanol. This precipitation procedure yields microparticulate solids of the poloxamer with mean particle sizes between 1 and 20 μm. The effects of various operational parameters, like the initial polymer concentration and the CO 2 content in the solution, on the resulting mean particle sizes and particle size distribution has been also studied." @default.
• W2024788823 created "2016-06-24" @default.
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• W2024788823 date "2008-12-01" @default.
• W2024788823 modified "2023-09-25" @default.
• W2024788823 title "Synergistic solubility behaviour of a polyoxyalkylene block co-polymer and its precipitation from liquid CO2-expanded ethanol as solid microparticles" @default.
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• W2024788823 doi "https://doi.org/10.1016/j.supflu.2008.07.019" @default.
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