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• W2024789664 abstract "The use of zeolites is no longer confined to the field of acid–base catalysis and adsorption but has expanded to other areas such as supramolecular catalysis, photochemistry, nanochemistry, and electrochemistry. This chapter emphasizes certain correlations and concepts that allow understanding zeolite synthesis in its broadest chemical sense. This approach is limited to the synthesis of aluminosilicate zeolites; the appropriate changes in the chemistry would allow application to other microporous metallosilicates as well. Hydrothermal synthesis of aluminosilicate zeolites involves a few elementary steps by which a mixture of Si and Al species, metal cations, organic molecules, and water is converted via an alkaline supersaturated solution into a microporous crystalline aluminosilicate. The complex chemical processes involved in this transformation can be denoted as “zeolitization.” The process of zeolitization is thermally activated, and it usually takes place at elevated temperatures to achieve high yield of crystals in an acceptable period of time. Because of the chemical phenomena occurring during zeolite genesis, the process can be divided into three basic steps: achievement of supersaturation, nucleation, and crystal growth. The ageing or ripening of the gel describes the time period and the phenomena occurring after the preparation of the gel when the gel is left below crystallization temperature." @default.
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• W2024789664 date "1994-01-01" @default.
• W2024789664 modified "2023-10-15" @default.
• W2024789664 title "Zeolites and their Mechanism of Synthesis" @default.
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• W2024789664 doi "https://doi.org/10.1016/s0167-2991(08)64074-4" @default.
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