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- W2024793837 abstract "Solvolysis of 1,1-diphenyl-1-X-ethane (1-X) [X = 4-nitrobenzoate (PNB), 3,5-dinitrobenzoate (DNB), AcO, MeOH+, EtOH+ or H2O+] was studied in 20 vol% dimethyl sulphoxide in water, in which specific salt effects are very small, and in 25 vol% acetonitrile in water. Substrates with negatively charged leaving groups yield more elimination product 1,1-diphenylethene (3) than those with uncharged groups, indicating the intermedicacy of ion pairs. Thus, three times more alkene is formed in the reactions of the substrates 1-OAc and 1-PNB than in the acid-catalysed hydrolysis of 1-OMe and 1-OAc. The substitution products may be formed via the solvent-equilibrated carbocation since the measured nucleophilic selectivities are very similar with different leaving groups." @default.
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- W2024793837 date "1992-06-01" @default.
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- W2024793837 title "Solvolysis of 1,1-diphenylethyl derivatives in highly aqueous media. Reaction via ion pairs" @default.
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- W2024793837 doi "https://doi.org/10.1002/poc.610050614" @default.
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