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• W2024795854 endingPage "4731" @default.
• W2024795854 startingPage "4727" @default.
• W2024795854 abstract "Abstract The structures of [( i Pr 3 P) 2 Cu(μ‐SSiMe 3 )(InMe 3 )] and [( i Pr 3 P) 2 Cu(μ‐SeSiMe 3 )(InMe 3 )] were determined by single‐crystal X‐ray diffraction. Both complexes are Lewis acid–base adducts of the InMe 3 acceptor and the chalcogen donor atom linking a Me 3 Si group and a ( i Pr 3 P) 2 Cu moiety. They are very unstable under atmospheric conditions and decompose at ambient temperatures. Results of DFT calculations for these complexes and the related hypothetical [(Me 3 P) 2 Cu(μ‐SSiMe 3 )(InMe 3 )] compound show that the unusual planar coordination of the chalcogen atoms is due to steric crowding." @default.
• W2024795854 created "2016-06-24" @default.
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• W2024795854 date "2013-08-21" @default.
• W2024795854 modified "2023-10-16" @default.
• W2024795854 title "Synthesis and Crystal Structures of [( <i>i</i> Pr ₃ P) ₂ Cu(μ‐ESiMe ₃ )(InMe ₃ )] (E = S, Se): Lewis Acid–Base Adducts with Chalcogen Atoms in Planar Coordination" @default.
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• W2024795854 doi "https://doi.org/10.1002/ejic.201300768" @default.
• W2024795854 hasPublicationYear "2013" @default.
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