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- W2024795879 abstract "Abstract. Greening tissues accumulate Mg-protoporphyrin monoester and a group of metalloporphyrins that exhibit fluorescence emission and excitation properties which are red-shifted with respect to Mg-protoporphyrin monoester. These metalloporphyrins are collectively termed longer wavelength metalloporphyrins and are presumed to be metabolic intermediates between Mg-protoporphyrin monoester (MPE) and protochlorophyllide. The longer wavelength metalloporphyrins, together with Mg-protoporphyrin monoester, are referred to as the MPE-equivalent. During the study of the biosynthesis of the components of the MPE-equivalent and the study of their conversion to protochlorophyllide in vitro, it was observed that Zn-protoporphyrin and its monoester were also formed. The latter compounds interfered with the determination of the MPE-equivalent. Simultaneous equations were derived and solved to yield an equation which permitted the determination of the amount of MPE-equivalent in the presence of Zn-protoporphyrins from the fluorescence emission spectrum of the mixture. Such determinations were made without prior segregation of the metalloporphyrins." @default.
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- W2024795879 date "1977-11-01" @default.
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- W2024795879 title "SPECTROFLUOROMETRIC DETERMINATION OF Mg-PROTOPORPHYRIN MONOESTER AND LONGER WAVELENGTH METALLOPORPHYRINS IN THE PRESENCE OF Zn-PROTOPORPHYRIN" @default.
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- W2024795879 doi "https://doi.org/10.1111/j.1751-1097.1977.tb07525.x" @default.
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