Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024798151> ?p ?o ?g. }
Showing items 1 to 82 of
82
with 100 items per page.
- W2024798151 endingPage "582" @default.
- W2024798151 startingPage "577" @default.
- W2024798151 abstract "The microwave spectra of cyclopropyl chloride and cyclopropyl cyanide have been studied and rotational constants for the Cl35 and Cl37 molecules of the chloride and for the normal molecule and two deuterated species of the cyanide have been determined. The two deuterated species are the cis and trans forms of C lim |H2–CHD–C lim |¯H–CN. For C3H5Cl35, A = 16 625±145 Mc, B = 3905.4±0.3 Mc, and C = 3622.5±0.3 Mc. For C3H5Cl37, A = 16085±415, B = 3810.4±0.5 Mc, and C = 3540.8±0.5 Mc. The following structure fits the rotational constants within the experimental errors: dC–C = 1.5131 A, dC–Cl = 1.7780 A, dC–H = 1.105 A, ≰HCH = 114°36′, ≰HCCl = 120°52.9′. For C3H5CN, A = 15 917 Mc, B = 3465.06 Mc, and C = 3286.22 Mc. For cis C3H4DCN, A = 14 543 Mc, B = 3419.34 Mc, and C = 3229.15 Mc. For trans C3H4DCN, A = 15 367 Mc, B = 3358.79 Mc, and C = 3161.26 Mc. The following structure fits the rotational constants B and C to an average of 1.5 Mc: dC–C(ring) = 1.5131 A, dC–C(CN) = 1.4679 A, dC–H = 1.112 A, dC≡N = 1.1574 A, ≰H–C–H = 115°35′, and ≰C(CN)−C−−H=119∘35′. Analysis of the quadrupole structure in C3H5Cl shows that eqQ along the C–Cl bond axis is —71.7 Mc for Cl35, indicating 23% ionic character. The asymmetry η = 0.156 for Cl35 indicates a double bond character of 4%." @default.
- W2024798151 created "2016-06-24" @default.
- W2024798151 creator A5007212288 @default.
- W2024798151 creator A5055860277 @default.
- W2024798151 date "1958-09-01" @default.
- W2024798151 modified "2023-10-17" @default.
- W2024798151 title "Microwave Studies of the Structure of Cyclopropyl Derivatives" @default.
- W2024798151 cites W1485545779 @default.
- W2024798151 cites W1880684506 @default.
- W2024798151 cites W1968754719 @default.
- W2024798151 cites W1993381979 @default.
- W2024798151 cites W2028793850 @default.
- W2024798151 cites W2033844788 @default.
- W2024798151 cites W2034290192 @default.
- W2024798151 cites W2044047677 @default.
- W2024798151 cites W2056214858 @default.
- W2024798151 cites W2064708825 @default.
- W2024798151 cites W2093432634 @default.
- W2024798151 cites W2331805683 @default.
- W2024798151 cites W4252300898 @default.
- W2024798151 doi "https://doi.org/10.1063/1.1744541" @default.
- W2024798151 hasPublicationYear "1958" @default.
- W2024798151 type Work @default.
- W2024798151 sameAs 2024798151 @default.
- W2024798151 citedByCount "27" @default.
- W2024798151 countsByYear W20247981512012 @default.
- W2024798151 crossrefType "journal-article" @default.
- W2024798151 hasAuthorship W2024798151A5007212288 @default.
- W2024798151 hasAuthorship W2024798151A5055860277 @default.
- W2024798151 hasConcept C113196181 @default.
- W2024798151 hasConcept C121332964 @default.
- W2024798151 hasConcept C145148216 @default.
- W2024798151 hasConcept C178790620 @default.
- W2024798151 hasConcept C179104552 @default.
- W2024798151 hasConcept C184779094 @default.
- W2024798151 hasConcept C185592680 @default.
- W2024798151 hasConcept C2182769 @default.
- W2024798151 hasConcept C2778455166 @default.
- W2024798151 hasConcept C2778695967 @default.
- W2024798151 hasConcept C31100168 @default.
- W2024798151 hasConcept C32909587 @default.
- W2024798151 hasConcept C39984356 @default.
- W2024798151 hasConcept C58364064 @default.
- W2024798151 hasConcept C71240020 @default.
- W2024798151 hasConcept C8010536 @default.
- W2024798151 hasConceptScore W2024798151C113196181 @default.
- W2024798151 hasConceptScore W2024798151C121332964 @default.
- W2024798151 hasConceptScore W2024798151C145148216 @default.
- W2024798151 hasConceptScore W2024798151C178790620 @default.
- W2024798151 hasConceptScore W2024798151C179104552 @default.
- W2024798151 hasConceptScore W2024798151C184779094 @default.
- W2024798151 hasConceptScore W2024798151C185592680 @default.
- W2024798151 hasConceptScore W2024798151C2182769 @default.
- W2024798151 hasConceptScore W2024798151C2778455166 @default.
- W2024798151 hasConceptScore W2024798151C2778695967 @default.
- W2024798151 hasConceptScore W2024798151C31100168 @default.
- W2024798151 hasConceptScore W2024798151C32909587 @default.
- W2024798151 hasConceptScore W2024798151C39984356 @default.
- W2024798151 hasConceptScore W2024798151C58364064 @default.
- W2024798151 hasConceptScore W2024798151C71240020 @default.
- W2024798151 hasConceptScore W2024798151C8010536 @default.
- W2024798151 hasIssue "3" @default.
- W2024798151 hasLocation W20247981511 @default.
- W2024798151 hasOpenAccess W2024798151 @default.
- W2024798151 hasPrimaryLocation W20247981511 @default.
- W2024798151 hasRelatedWork W157199786 @default.
- W2024798151 hasRelatedWork W1980132893 @default.
- W2024798151 hasRelatedWork W1997901467 @default.
- W2024798151 hasRelatedWork W2021947091 @default.
- W2024798151 hasRelatedWork W2023326820 @default.
- W2024798151 hasRelatedWork W2030848362 @default.
- W2024798151 hasRelatedWork W2059943071 @default.
- W2024798151 hasRelatedWork W2082451975 @default.
- W2024798151 hasRelatedWork W2998977823 @default.
- W2024798151 hasRelatedWork W4234558390 @default.
- W2024798151 hasVolume "29" @default.
- W2024798151 isParatext "false" @default.
- W2024798151 isRetracted "false" @default.
- W2024798151 magId "2024798151" @default.
- W2024798151 workType "article" @default.