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- W2024802963 abstract "The second-order rate constants for the oxidations of d-glucopyranose 6-phosphate and d-ribofuranose 5-phosphate by vanadium(V) in perchloric acid media have been measured spectrophotometrically in the visible region. The order with respect to [H+] is less than unity for each reaction. The enthalpy and entropy of activations of the reactions are higher than those for the corresponding two-electron oxidations by chromium(VI). The oxidation involves free-radical intermediates." @default.
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- W2024802963 date "1986-01-01" @default.
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- W2024802963 title "Kinetics and mechanism of oxidation of d-glucopyranose 6-phosphate and d-ribofuranose 5-phosphate by vanadium(V) in perchloric acid media" @default.
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- W2024802963 doi "https://doi.org/10.1016/s0008-6215(00)90429-4" @default.
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