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• W2024807687 abstract "AbstractYttria-stabilized zirconia (YSZ) single crystals (for 9.5 and 18 mol% yttria) were irradiated at room temperature (RT) by X-rays (W white spectrum) and 2.5-MeV electrons. The growth curves of the so-called T-centre (for trigonal centre, i.e. Zr3+ sitting in a trigonal symmetry site) were studied as a function of absorbed dose, or irradiation time, by UV–visible optical absorption (OA) spectroscopy and X-band electron paramagnetic resonance spectroscopy. The defect concentration at saturation and the production rate are increased by a factor around two for 18 mol% yttria with respect to 9.5 mol%. Defect decay was then followed after irradiation by OA spectroscopy as a function of ageing time at RT. Growth and decay curves of the T-centre are modelled on the basis of rate equations of charge-exchange reactions with the zirconium lattice ions. Increase in yttrium content is thought to decrease hole trapping on Zr3+ ions, thereby enhancing T-centre formation.Keywords: yttria-stabilized zirconiaX-ray irradiationelectron irradiationcolour centresoptical absorption spectroscopyelectron paramagnetic spectroscopyPACS codes: 61.80.-x78.40.-q76.30.Mi61.72.Cc" @default.
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• W2024807687 date "2014-11-13" @default.
• W2024807687 modified "2023-09-30" @default.
• W2024807687 title "Colour centre production in yttria-stabilized zirconia by X-ray and electron irradiations: effect of yttria content" @default.
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• W2024807687 doi "https://doi.org/10.1080/14786435.2014.977369" @default.
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