Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024808497> ?p ?o ?g. }
- W2024808497 endingPage "130" @default.
- W2024808497 startingPage "118" @default.
- W2024808497 abstract "Surface complexes of β-picoline, 3-pyridine-carbaldehyde and nicotinic acid on 20 wt.% V2O5/TiO2 catalysts containing 0.07 and 6.3l wt.% SO42− were studied by FTIR spectroscopy and temperature programmed reaction technique. The water (both H2O and D2O), pyridine and β-picoline were used as molecular probes for identification of surface acidity and the structure of sulfate species. Both samples possess Lewis and Brönsted acidic sites. β-Picoline, 3-pyridine-carbaldehyde and nicotinic acid form surface complexes of similar structure on both studied catalysts. But high sulfated catalyst contains stronger Brönsted sites in greater amount. It leads to the formation of stronger bound surface complexes of β-picoline, 3-pyridine-carbaldehyde and nicotinic acid. The strongly bound surface complexes are transformed into by-products (COx, pyridine and 3-cyanopyridine). It resulted in substantial reduction of nicotinic acid yield." @default.
- W2024808497 created "2016-06-24" @default.
- W2024808497 creator A5030511244 @default.
- W2024808497 creator A5052246045 @default.
- W2024808497 creator A5065696956 @default.
- W2024808497 creator A5084636487 @default.
- W2024808497 date "2013-12-01" @default.
- W2024808497 modified "2023-09-26" @default.
- W2024808497 title "FTIR study of β-picoline and pyridine-3-carbaldehyde transformation on V–Ti–O catalysts. The effect of sulfate content on β-picoline oxidation into nicotinic acid" @default.
- W2024808497 cites W1516075933 @default.
- W2024808497 cites W181821807 @default.
- W2024808497 cites W1966683907 @default.
- W2024808497 cites W1969808987 @default.
- W2024808497 cites W1970542887 @default.
- W2024808497 cites W1978077339 @default.
- W2024808497 cites W1978199148 @default.
- W2024808497 cites W1978338966 @default.
- W2024808497 cites W1985796946 @default.
- W2024808497 cites W1989763886 @default.
- W2024808497 cites W1990322149 @default.
- W2024808497 cites W1992965598 @default.
- W2024808497 cites W1994200564 @default.
- W2024808497 cites W1995057489 @default.
- W2024808497 cites W1998197103 @default.
- W2024808497 cites W1998718581 @default.
- W2024808497 cites W2005427959 @default.
- W2024808497 cites W2015518172 @default.
- W2024808497 cites W2016037683 @default.
- W2024808497 cites W2021985928 @default.
- W2024808497 cites W2029988217 @default.
- W2024808497 cites W2036219041 @default.
- W2024808497 cites W2037489860 @default.
- W2024808497 cites W2039890906 @default.
- W2024808497 cites W2043666014 @default.
- W2024808497 cites W2044169338 @default.
- W2024808497 cites W2047496511 @default.
- W2024808497 cites W2048757971 @default.
- W2024808497 cites W2070319601 @default.
- W2024808497 cites W2072783461 @default.
- W2024808497 cites W2073887016 @default.
- W2024808497 cites W2081186552 @default.
- W2024808497 cites W2086264351 @default.
- W2024808497 cites W2093778033 @default.
- W2024808497 cites W2139519254 @default.
- W2024808497 cites W2164333322 @default.
- W2024808497 cites W2170848987 @default.
- W2024808497 cites W2329895362 @default.
- W2024808497 cites W2408641632 @default.
- W2024808497 cites W2950279532 @default.
- W2024808497 cites W2951594727 @default.
- W2024808497 cites W2951916948 @default.
- W2024808497 doi "https://doi.org/10.1016/j.molcata.2013.09.028" @default.
- W2024808497 hasPublicationYear "2013" @default.
- W2024808497 type Work @default.
- W2024808497 sameAs 2024808497 @default.
- W2024808497 citedByCount "8" @default.
- W2024808497 countsByYear W20248084972015 @default.
- W2024808497 countsByYear W20248084972016 @default.
- W2024808497 countsByYear W20248084972018 @default.
- W2024808497 countsByYear W20248084972020 @default.
- W2024808497 countsByYear W20248084972021 @default.
- W2024808497 crossrefType "journal-article" @default.
- W2024808497 hasAuthorship W2024808497A5030511244 @default.
- W2024808497 hasAuthorship W2024808497A5052246045 @default.
- W2024808497 hasAuthorship W2024808497A5065696956 @default.
- W2024808497 hasAuthorship W2024808497A5084636487 @default.
- W2024808497 hasConcept C13965031 @default.
- W2024808497 hasConcept C155647269 @default.
- W2024808497 hasConcept C161790260 @default.
- W2024808497 hasConcept C163638829 @default.
- W2024808497 hasConcept C170493617 @default.
- W2024808497 hasConcept C178790620 @default.
- W2024808497 hasConcept C179104552 @default.
- W2024808497 hasConcept C185592680 @default.
- W2024808497 hasConcept C188987157 @default.
- W2024808497 hasConcept C2776272617 @default.
- W2024808497 hasConcept C2778343803 @default.
- W2024808497 hasConcept C2779485729 @default.
- W2024808497 hasConcept C55493867 @default.
- W2024808497 hasConcept C79878483 @default.
- W2024808497 hasConceptScore W2024808497C13965031 @default.
- W2024808497 hasConceptScore W2024808497C155647269 @default.
- W2024808497 hasConceptScore W2024808497C161790260 @default.
- W2024808497 hasConceptScore W2024808497C163638829 @default.
- W2024808497 hasConceptScore W2024808497C170493617 @default.
- W2024808497 hasConceptScore W2024808497C178790620 @default.
- W2024808497 hasConceptScore W2024808497C179104552 @default.
- W2024808497 hasConceptScore W2024808497C185592680 @default.
- W2024808497 hasConceptScore W2024808497C188987157 @default.
- W2024808497 hasConceptScore W2024808497C2776272617 @default.
- W2024808497 hasConceptScore W2024808497C2778343803 @default.
- W2024808497 hasConceptScore W2024808497C2779485729 @default.
- W2024808497 hasConceptScore W2024808497C55493867 @default.
- W2024808497 hasConceptScore W2024808497C79878483 @default.
- W2024808497 hasLocation W20248084971 @default.
- W2024808497 hasOpenAccess W2024808497 @default.
- W2024808497 hasPrimaryLocation W20248084971 @default.
- W2024808497 hasRelatedWork W1969256641 @default.