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- W2024816473 abstract "Poly(ethyleneoxide) complexed with ${mathrm{NH}}_{4}$SCN (${mathrm{NH}}_{4}$SCN wt. % varying from 0 to 20% corresponding to [${mathrm{NH}}_{4}^{+}$]/[ethyleneoxide] 0 to 0.146) have been studied as a possible ion conducting polymer. Good quality films could be obtained only for low salt concentration (${mathrm{NH}}_{4}$SCN wt. %=0--5 % or [${mathrm{NH}}_{4}^{+}$]/[ethyleneoxide] is 0 to ensuremath{le}0.031), on which detailed ion transport studies have been carried out. These studies showed that ${mathrm{H}}^{+}$ as well as ${mathrm{SCN}}^{mathrm{ensuremath{-}}}$ ions are mobile. However, films were rubbery (partly liquidus) for higher salt concentration. It is shown that ${mathrm{SCN}}^{mathrm{ensuremath{-}}}$ aggregation plays a dominant role. Special conditions were created to obtain dense branched structure of the size 5--10 mm of (SCN${)}_{mathit{x}}$ in the PEO:${mathrm{NH}}_{4}$SCN film for 20 wt. % ${mathrm{NH}}_{4}$ SCN." @default.
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- W2024816473 date "1995-07-01" @default.
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- W2024816473 title "Dense branched growth of (SCN<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mo>)</mml:mo></mml:mrow><mml:mrow><mml:mi mathvariant=italic>x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>and ion transport in the poly(ethyleneoxide)<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>NH</mml:mi></mml:mrow><mml:mrow><mml:mn>4</mml:mn></mml:mrow></mml:…" @default.
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- W2024816473 doi "https://doi.org/10.1103/physrevb.52.225" @default.
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