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- W2024838045 abstract "Photochemical reaction of a new aromatic amine with dual reaction sites for the ring closure, 1, 3, 5-tris(diphenylamino)benzene (TDAB), was investigated to clarify its photochemical reaction course and the effect of oxygen on the photochemical reaction. It was found that TDAB undergoes photocyclization reaction in solution in the absence or presence of oxygen to produce N-phenyl-2, 4-bis(diphenylamino)carbazole. The product analysis and the result of laser flash photolysis indicate that the reaction mechanism for the photocyclization of TDAB is different between the deaerated and oxygen-saturated systems. Photocyclization reaction of TDAB in the absence of oxygen takes place via the electronically excited triplet state of TDAB, followed by the formation of the dihydrocarbazole. In the presence of oxygen, the dihydrocarbazole radical cation is suggested to be involved as an intermediate." @default.
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- W2024838045 date "1999-01-01" @default.
- W2024838045 modified "2023-09-24" @default.
- W2024838045 title "Photochemical Reaction of 1,3,5-Tris(diphenylamino)benzene." @default.
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- W2024838045 doi "https://doi.org/10.2494/photopolymer.12.777" @default.
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