FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024839952> ?p ?o ?g. }

• W2024839952 endingPage "1742" @default.
• W2024839952 startingPage "1729" @default.
• W2024839952 abstract "Abstract The binuclear copper complex [Cu(H2slox)]2 (1) and heterobinuclear copper and molybdenum complexes [Cu(slox)MoO2(A)2] (slox = tetranegative disalicylaldehyde oxaloyldihydrazone) (A = H2O (2), py (3), 2-pic (4), 3-pic (5), 4-pic (6)) and [Cu(slox)MoO2(NN)] (NN = bpy (7) and phen (8)) have been synthesized from disalicylaldehyde oxaloyldihydrazone in methanol and characterized by various physico-chemical and spectroscopic techniques. The stoichiometry of the complexes has been established based on elemental analyses and thermoanalytical studies. The µ eff values for the complexes rule out metal–metal interaction between the metal centers in the structural unit of the complexes. The dihydrazone has keto-enol forms; in 1, it is a dibasic tetradentate bridging ligand in enol form and in heterobinuclear complexes as a tetrabasic hexadentate bridging ligand. Electronic spectra of the complexes show that copper(II) is square-planar in binuclear and heterobinuclear complexes; molybdenum is a distorted octahedral stereochemistry in heterobinuclear complexes. EPR spectra suggest that in all complexes, the unpaired electron is in the d x 2− y 2 orbital of copper and that the copper in heterobinuclear complexes is tetrahedrally distorted. Keywords: Heterobinuclear complexesCopper(II)Dioxomolybdenum(VI)Disalicylaldehyde oxaloyldihydrazoneSpectral studies" @default.
• W2024839952 created "2016-06-24" @default.
• W2024839952 creator A5044863479 @default.
• W2024839952 creator A5050474946 @default.
• W2024839952 creator A5055238713 @default.
• W2024839952 creator A5064409242 @default.
• W2024839952 creator A5066299666 @default.
• W2024839952 creator A5081812375 @default.
• W2024839952 creator A5091865032 @default.
• W2024839952 creator A5036525493 @default.
• W2024839952 date "2011-05-19" @default.
• W2024839952 modified "2023-10-10" @default.
• W2024839952 title "Synthesis and characterization of a binuclear copper(II) complex [Cu(H₂slox)]₂ from polyfunctional disalicylaldehyde oxaloyldihydrazone and its heterobinuclear copper(II) and molybdenum(VI) complexes" @default.
• W2024839952 cites W1499735349 @default.
• W2024839952 cites W1969789360 @default.
• W2024839952 cites W1979834447 @default.
• W2024839952 cites W1984035796 @default.
• W2024839952 cites W1991586379 @default.
• W2024839952 cites W1998722626 @default.
• W2024839952 cites W2002896478 @default.
• W2024839952 cites W2003875927 @default.
• W2024839952 cites W2006680249 @default.
• W2024839952 cites W2006948764 @default.
• W2024839952 cites W2014378461 @default.
• W2024839952 cites W2018453627 @default.
• W2024839952 cites W2024363003 @default.
• W2024839952 cites W2026047984 @default.
• W2024839952 cites W2028291957 @default.
• W2024839952 cites W2032630526 @default.
• W2024839952 cites W2035591010 @default.
• W2024839952 cites W2053205158 @default.
• W2024839952 cites W2060475189 @default.
• W2024839952 cites W2069233782 @default.
• W2024839952 cites W2077721910 @default.
• W2024839952 cites W2083769831 @default.
• W2024839952 cites W2084192500 @default.
• W2024839952 cites W2084358376 @default.
• W2024839952 cites W2084616197 @default.
• W2024839952 cites W2087921516 @default.
• W2024839952 cites W2091203663 @default.
• W2024839952 cites W2117425806 @default.
• W2024839952 cites W2161288829 @default.
• W2024839952 cites W2315823218 @default.
• W2024839952 cites W2336472145 @default.
• W2024839952 cites W3138363965 @default.
• W2024839952 cites W76240273 @default.
• W2024839952 doi "https://doi.org/10.1080/00958972.2011.580845" @default.
• W2024839952 hasPublicationYear "2011" @default.
• W2024839952 type Work @default.
• W2024839952 sameAs 2024839952 @default.
• W2024839952 citedByCount "16" @default.
• W2024839952 countsByYear W20248399522012 @default.
• W2024839952 countsByYear W20248399522013 @default.
• W2024839952 countsByYear W20248399522014 @default.
• W2024839952 countsByYear W20248399522015 @default.
• W2024839952 countsByYear W20248399522016 @default.
• W2024839952 countsByYear W20248399522017 @default.
• W2024839952 countsByYear W20248399522019 @default.
• W2024839952 countsByYear W20248399522020 @default.
• W2024839952 crossrefType "journal-article" @default.
• W2024839952 hasAuthorship W2024839952A5036525493 @default.
• W2024839952 hasAuthorship W2024839952A5044863479 @default.
• W2024839952 hasAuthorship W2024839952A5050474946 @default.
• W2024839952 hasAuthorship W2024839952A5055238713 @default.
• W2024839952 hasAuthorship W2024839952A5064409242 @default.
• W2024839952 hasAuthorship W2024839952A5066299666 @default.
• W2024839952 hasAuthorship W2024839952A5081812375 @default.
• W2024839952 hasAuthorship W2024839952A5091865032 @default.
• W2024839952 hasConcept C115624301 @default.
• W2024839952 hasConcept C116569031 @default.
• W2024839952 hasConcept C121332964 @default.
• W2024839952 hasConcept C122191521 @default.
• W2024839952 hasConcept C161790260 @default.
• W2024839952 hasConcept C170493617 @default.
• W2024839952 hasConcept C178790620 @default.
• W2024839952 hasConcept C179104552 @default.
• W2024839952 hasConcept C185592680 @default.
• W2024839952 hasConcept C186927785 @default.
• W2024839952 hasConcept C187961010 @default.
• W2024839952 hasConcept C188027245 @default.
• W2024839952 hasConcept C198819137 @default.
• W2024839952 hasConcept C2777495281 @default.
• W2024839952 hasConcept C32909587 @default.
• W2024839952 hasConcept C46141821 @default.
• W2024839952 hasConcept C544153396 @default.
• W2024839952 hasConcept C544778455 @default.
• W2024839952 hasConcept C549387045 @default.
• W2024839952 hasConcept C55493867 @default.
• W2024839952 hasConcept C8010536 @default.
• W2024839952 hasConceptScore W2024839952C115624301 @default.
• W2024839952 hasConceptScore W2024839952C116569031 @default.
• W2024839952 hasConceptScore W2024839952C121332964 @default.
• W2024839952 hasConceptScore W2024839952C122191521 @default.
• W2024839952 hasConceptScore W2024839952C161790260 @default.
• W2024839952 hasConceptScore W2024839952C170493617 @default.
• W2024839952 hasConceptScore W2024839952C178790620 @default.
• W2024839952 hasConceptScore W2024839952C179104552 @default.
• W2024839952 hasConceptScore W2024839952C185592680 @default.

• next