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• W2024841738 endingPage "1180" @default.
• W2024841738 startingPage "1171" @default.
• W2024841738 abstract "Crystal-structure refinements were done on Li-bearing muscovite-2 M 1 crystals from microgranite and granitic pegmatite rocks in order to characterize their crystal chemistry and their relationships with muscovite and trioctahedral lithium-containing micas. In addition to the substitution mechanism [6] Li + [6] Al 3+ −1 [4] Al 3+ −2 [4] Si 4+ 2 , Li-bearing muscovite shows additional substitutions, such as mechanism [6] Li + [6] Fe 2+ [6] Al 3+ −1 [6] □ −1 , indicating that the structure deviates from ideal dioctahedral character. Single-crystal X-ray-diffraction data were collected for five crystals in space group C 2/ c ; the agreement factor, R obs , varies between 0.033 and 0.042. The mean tetrahedral cation–oxygen atom distances range from 1.637 to 1.646 A and from 1.629 to 1.647 A for T 1 and T 2 sites, respectively. Variation in T –O> distances is associated with the Li + /(Li + + Al 3+ ) ratio, octahedral M 2 site expansion (9.30 ≤ volume M2 ≤ 9.90 A 3 ) and reduction in size of the M 1 site. Moreover, as the Li + /(Li + + Al 3+ ) ratio increases, the silicate ring becomes less distorted (5.9 ≤ α ≤ 11.4°), the basal oxygen-atom planes become less corrugated (0.147 ≤ Δ z ≤ 0.232 A), and the interlayer separation narrows (3.337 ≤ interlayer separation ≤ 3.422 A)." @default.
• W2024841738 created "2016-06-24" @default.
• W2024841738 creator A5001607650 @default.
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• W2024841738 date "2001-08-01" @default.
• W2024841738 modified "2023-10-03" @default.
• W2024841738 title "CRYSTAL STRUCTURE AND CRYSTAL CHEMISTRY OF LITHIUM-BEARING MUSCOVITE-2M1" @default.
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• W2024841738 doi "https://doi.org/10.2113/gscanmin.39.4.1171" @default.
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