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• W2024842557 startingPage "8452" @default.
• W2024842557 abstract "Abstract Molecular switches based on helical tetrasubstituted alkenes, substituted with either electron‐withdrawing (CF 3 , F, CN; 2 a – c , 3 a , c ) or ‐donating substituents (Me, OMe; 2 d , e ), have been synthesized from acyclic precursors 4 and 5 in a domino carbopalladation/Stille reaction. This palladium‐catalyzed process allowed the rapid assembly of two CC bonds, two six‐membered rings, and the tetrasubstituted double bond in a completely diastereoselective fashion. The electronic effects of the substituents on the overall switching process were investigated by alternating irradiation of two different wavelength regions. Although the substituents had only a small influence on the absorption maxima, drastic differences in the switching behavior were observed." @default.
• W2024842557 created "2016-06-24" @default.
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• W2024842557 date "2011-06-10" @default.
• W2024842557 modified "2023-10-18" @default.
• W2024842557 title "Synthesis and Photochemical Investigations of Tetrasubstituted Alkenes as Molecular Switches-The Effect of Substituents" @default.
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• W2024842557 doi "https://doi.org/10.1002/chem.201003559" @default.
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