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- W2024842905 abstract "The specific heats, which are given with absolute value, of Rochelle salt--ammonium Rochelle salt mixed crystals $({mathrm{RS}}_{1ensuremath{-}x}ensuremath{-}{mathrm{ARS}}_{x})$ in a region $0.18l~xl~0.9$ have been measured between about 10 K and 300 K by an ac calorimetric method. A very small anomaly was found around the transition for any x. It becomes larger as x increases. The anomalies have been well described using the Landau-type free energy expanded to the sixth order of polarization. It was found that, as x increases, the transition point approaches the tricritical point at which a crossover from the second-order phase transition to the first-order one takes place. Transition entropy has been calculated from the anomalous specific heat. It increases from about $8%$ to about $55%$ of $Rmathrm{ln}2$ with increasing x in the measured region. Very small values for small x in this region suggest the displacivelike character in the phase transition. And the order-disorder motion contributes more and more to the phase transition with increasing x." @default.
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- W2024842905 date "2000-11-01" @default.
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- W2024842905 title "Calorimetric measurements of the phase transition in Rochelle salt–ammonium Rochelle salt mixed crystals" @default.
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- W2024842905 doi "https://doi.org/10.1103/physrevb.62.12040" @default.
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