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- W2024852938 abstract "The crystal growth of manganese sulphide, selenide and telluride by chemical vapor transport in a closed system with AlCl3 as a carrier is studied. The composition of the vapor phase temperature and for various total pressure is calculated using thermodynamic data. The role of gaseous complexes of MnAl2Cl8 and MnAl3Cl11 in MnX : AlCl3 (X = S, Se, Te) systems in comparison with MnCl2 in MnX : Cl2 systems is discussed. The partial pressures of the manganese complexes and the solubility of the solid state body in a gas phase change strongly with temperature unlike the case of MnCl2 in the MnX : Cl2 system. The stability of manganese complexes increases with increasing total pressure in the systems up to 1200 K. The crystals were grown under the following conditions: The source temperature (T3) was about 900 K and ΔT was 15–25°C for ΣP = 1, 2 and 3 atm. Cubic, MnS and MnSe crystals (octahedra) were 5 x 5 x 7 mm3 and hexagonal MnTe platelets 1–2 mm in diameter." @default.
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- W2024852938 date "1980-07-01" @default.
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- W2024852938 title "The role of Mn-Al-Cl complexes in crystal growth of MnS, MnSe and MnTe by chemical vapor transport" @default.
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- W2024852938 doi "https://doi.org/10.1016/0022-0248(80)90131-1" @default.
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