Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024853336> ?p ?o ?g. }
- W2024853336 endingPage "5927" @default.
- W2024853336 startingPage "5921" @default.
- W2024853336 abstract "The alkyldisulfanido zinc complexes TpiPr,iPrZn(SSR) and TpPh,MeZn(SSR) where TpiPr,iPr is hydridotris-((3,5-isopropyl)pyrazolyl)borate, TpPh,Me is hydridotris-((3-phenyl,5-methyl)pyrazolyl)borate, and (SSR) is tert-butyldisulfanido or triphenylmethanedisulfanido were synthesized by reaction between the corresponding hydroxo complexes TpZn(OH) and the synthetic persulfide RSSH. All the complexes were characterized by elemental analysis and 1H NMR spectroscopy, and representative members of the class were also structurally characterized. The reactivity of the alkyldisulfanido TpZn(SSR) complexes with thiols was studied. In the absence of base, a simple exchange reaction between the alkyldisulfanido ligand and the thiol was observed in dichloromethane; when in the presence of base, the corresponding hydrogen(sulfido) complexes TpZn(SH) were obtained. The mechanism of the latter reaction has been studied and does not involve the coordinated alkyldisulfanido group. Reaction of the hydrogen(sulfido) complexes TpiPr,iPrZn(SH) with the thiosulfonate PhCH2S-SO2CF3 did not yield the expected alkyldisulfanido complex but benzyltrisulfide and a new complex tentatively assigned as TpiPr,iPrZn(O2SCF3)." @default.
- W2024853336 created "2016-06-24" @default.
- W2024853336 creator A5028644126 @default.
- W2024853336 creator A5034308900 @default.
- W2024853336 creator A5062602963 @default.
- W2024853336 creator A5075573518 @default.
- W2024853336 creator A5087525957 @default.
- W2024853336 date "2009-06-10" @default.
- W2024853336 modified "2023-10-09" @default.
- W2024853336 title "Synthesis, Characterization, and Reactivity of Alkyldisulfanido Zinc Complexes" @default.
- W2024853336 cites W1680110737 @default.
- W2024853336 cites W1976966377 @default.
- W2024853336 cites W1982729369 @default.
- W2024853336 cites W1987340301 @default.
- W2024853336 cites W1989324239 @default.
- W2024853336 cites W1994262781 @default.
- W2024853336 cites W1996778213 @default.
- W2024853336 cites W1997237922 @default.
- W2024853336 cites W2004135112 @default.
- W2024853336 cites W2015028228 @default.
- W2024853336 cites W2017496572 @default.
- W2024853336 cites W2018093242 @default.
- W2024853336 cites W2020569118 @default.
- W2024853336 cites W2020599071 @default.
- W2024853336 cites W2030182333 @default.
- W2024853336 cites W2031103803 @default.
- W2024853336 cites W2032918456 @default.
- W2024853336 cites W2033231456 @default.
- W2024853336 cites W2034380234 @default.
- W2024853336 cites W2037191427 @default.
- W2024853336 cites W2037965362 @default.
- W2024853336 cites W2040138153 @default.
- W2024853336 cites W2043349645 @default.
- W2024853336 cites W2043809520 @default.
- W2024853336 cites W2049753196 @default.
- W2024853336 cites W2051079121 @default.
- W2024853336 cites W2057328219 @default.
- W2024853336 cites W2059020082 @default.
- W2024853336 cites W2059803436 @default.
- W2024853336 cites W2065577242 @default.
- W2024853336 cites W2066916734 @default.
- W2024853336 cites W2070991046 @default.
- W2024853336 cites W2072516212 @default.
- W2024853336 cites W2072621673 @default.
- W2024853336 cites W2073346894 @default.
- W2024853336 cites W2073845244 @default.
- W2024853336 cites W2079662840 @default.
- W2024853336 cites W2085576133 @default.
- W2024853336 cites W2089894297 @default.
- W2024853336 cites W2091043643 @default.
- W2024853336 cites W2102472842 @default.
- W2024853336 cites W2106171481 @default.
- W2024853336 cites W2122397133 @default.
- W2024853336 cites W2125935442 @default.
- W2024853336 cites W2161788422 @default.
- W2024853336 cites W2179083603 @default.
- W2024853336 cites W2327720342 @default.
- W2024853336 cites W2950554087 @default.
- W2024853336 cites W2950685372 @default.
- W2024853336 cites W3004587489 @default.
- W2024853336 doi "https://doi.org/10.1021/ic900238v" @default.
- W2024853336 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19514736" @default.
- W2024853336 hasPublicationYear "2009" @default.
- W2024853336 type Work @default.
- W2024853336 sameAs 2024853336 @default.
- W2024853336 citedByCount "41" @default.
- W2024853336 countsByYear W20248533362016 @default.
- W2024853336 countsByYear W20248533362017 @default.
- W2024853336 countsByYear W20248533362018 @default.
- W2024853336 countsByYear W20248533362019 @default.
- W2024853336 countsByYear W20248533362020 @default.
- W2024853336 countsByYear W20248533362021 @default.
- W2024853336 countsByYear W20248533362022 @default.
- W2024853336 countsByYear W20248533362023 @default.
- W2024853336 crossrefType "journal-article" @default.
- W2024853336 hasAuthorship W2024853336A5028644126 @default.
- W2024853336 hasAuthorship W2024853336A5034308900 @default.
- W2024853336 hasAuthorship W2024853336A5062602963 @default.
- W2024853336 hasAuthorship W2024853336A5075573518 @default.
- W2024853336 hasAuthorship W2024853336A5087525957 @default.
- W2024853336 hasConcept C104264131 @default.
- W2024853336 hasConcept C116569031 @default.
- W2024853336 hasConcept C134121241 @default.
- W2024853336 hasConcept C134306372 @default.
- W2024853336 hasConcept C142724271 @default.
- W2024853336 hasConcept C155647269 @default.
- W2024853336 hasConcept C170493617 @default.
- W2024853336 hasConcept C178790620 @default.
- W2024853336 hasConcept C185592680 @default.
- W2024853336 hasConcept C188027245 @default.
- W2024853336 hasConcept C191897082 @default.
- W2024853336 hasConcept C192562407 @default.
- W2024853336 hasConcept C204787440 @default.
- W2024853336 hasConcept C2776910235 @default.
- W2024853336 hasConcept C2780400988 @default.
- W2024853336 hasConcept C2780471494 @default.
- W2024853336 hasConcept C2781324293 @default.
- W2024853336 hasConcept C33923547 @default.