Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024854034> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W2024854034 endingPage "3461" @default.
- W2024854034 startingPage "3452" @default.
- W2024854034 abstract "Infrared and Raman spectra are presented for monomeric and dimeric thallous halide species (TlF, Tl2F2, TlCl, and Tl2Cl2) isolated in argon matrices. From these results it is concluded that both the Tl2F2 and Tl2Cl2 molecules have planar rhombic structures rather than linear configurations as previously proposed on the basis of mass spectroscopic, infrared, and photoelectron studies. Entropy calculations and other arguments are presented to resolve this discrepancy. Our structural conclusion for Tl2F2 is in good accord with a very recent electron diffraction investigation of Tl2F2 and the structural parameters and vibrational amplitudes obtained in that work are incorporated with our frequencies in a normal coordinate analysis. Force fields are obtained for both Tl2F2 and Tl2Cl2 and a very large amplitude (31°) is calculated for the out of plane bending coordinate of Tl2F2. Assuming that the bonding in this compound is largely ionic, an average instantaneous vibrational dipole moment of 3.7 D is deduced. This very large value in a ’’nonpolar’’ molecule is in good agreement with a novel electron scattering experiment on Tl2F2 molecular beams in which vibrational dipoles in the range 2–8 D were recently reported." @default.
- W2024854034 created "2016-06-24" @default.
- W2024854034 creator A5081594038 @default.
- W2024854034 creator A5084809766 @default.
- W2024854034 date "1975-10-15" @default.
- W2024854034 modified "2023-10-18" @default.
- W2024854034 title "Infrared and Raman spectra and structures of matrix isolated thallous halide dimers: Tl2F2 and Tl2Cl2" @default.
- W2024854034 cites W1966804506 @default.
- W2024854034 cites W1990487154 @default.
- W2024854034 cites W2006371582 @default.
- W2024854034 cites W2009303348 @default.
- W2024854034 cites W2012270851 @default.
- W2024854034 cites W2021703025 @default.
- W2024854034 cites W2025538778 @default.
- W2024854034 cites W2037731165 @default.
- W2024854034 cites W2045503661 @default.
- W2024854034 cites W2048631821 @default.
- W2024854034 cites W2050114347 @default.
- W2024854034 cites W2050904321 @default.
- W2024854034 cites W2056899555 @default.
- W2024854034 cites W2139304231 @default.
- W2024854034 cites W2325313095 @default.
- W2024854034 cites W2327329440 @default.
- W2024854034 cites W2334913438 @default.
- W2024854034 doi "https://doi.org/10.1063/1.431782" @default.
- W2024854034 hasPublicationYear "1975" @default.
- W2024854034 type Work @default.
- W2024854034 sameAs 2024854034 @default.
- W2024854034 citedByCount "40" @default.
- W2024854034 countsByYear W20248540342015 @default.
- W2024854034 crossrefType "journal-article" @default.
- W2024854034 hasAuthorship W2024854034A5081594038 @default.
- W2024854034 hasAuthorship W2024854034A5084809766 @default.
- W2024854034 hasConcept C120665830 @default.
- W2024854034 hasConcept C121332964 @default.
- W2024854034 hasConcept C145148216 @default.
- W2024854034 hasConcept C147597530 @default.
- W2024854034 hasConcept C153642686 @default.
- W2024854034 hasConcept C158355884 @default.
- W2024854034 hasConcept C169573571 @default.
- W2024854034 hasConcept C173523689 @default.
- W2024854034 hasConcept C178790620 @default.
- W2024854034 hasConcept C184779094 @default.
- W2024854034 hasConcept C185592680 @default.
- W2024854034 hasConcept C207114421 @default.
- W2024854034 hasConcept C2182769 @default.
- W2024854034 hasConcept C32909587 @default.
- W2024854034 hasConcept C40003534 @default.
- W2024854034 hasConcept C41999313 @default.
- W2024854034 hasConcept C77557913 @default.
- W2024854034 hasConceptScore W2024854034C120665830 @default.
- W2024854034 hasConceptScore W2024854034C121332964 @default.
- W2024854034 hasConceptScore W2024854034C145148216 @default.
- W2024854034 hasConceptScore W2024854034C147597530 @default.
- W2024854034 hasConceptScore W2024854034C153642686 @default.
- W2024854034 hasConceptScore W2024854034C158355884 @default.
- W2024854034 hasConceptScore W2024854034C169573571 @default.
- W2024854034 hasConceptScore W2024854034C173523689 @default.
- W2024854034 hasConceptScore W2024854034C178790620 @default.
- W2024854034 hasConceptScore W2024854034C184779094 @default.
- W2024854034 hasConceptScore W2024854034C185592680 @default.
- W2024854034 hasConceptScore W2024854034C207114421 @default.
- W2024854034 hasConceptScore W2024854034C2182769 @default.
- W2024854034 hasConceptScore W2024854034C32909587 @default.
- W2024854034 hasConceptScore W2024854034C40003534 @default.
- W2024854034 hasConceptScore W2024854034C41999313 @default.
- W2024854034 hasConceptScore W2024854034C77557913 @default.
- W2024854034 hasIssue "8" @default.
- W2024854034 hasLocation W20248540341 @default.
- W2024854034 hasOpenAccess W2024854034 @default.
- W2024854034 hasPrimaryLocation W20248540341 @default.
- W2024854034 hasRelatedWork W1973087998 @default.
- W2024854034 hasRelatedWork W2008697 @default.
- W2024854034 hasRelatedWork W2021807889 @default.
- W2024854034 hasRelatedWork W2025570563 @default.
- W2024854034 hasRelatedWork W2031791123 @default.
- W2024854034 hasRelatedWork W2048077761 @default.
- W2024854034 hasRelatedWork W2094803125 @default.
- W2024854034 hasRelatedWork W2169490435 @default.
- W2024854034 hasRelatedWork W3023947763 @default.
- W2024854034 hasRelatedWork W4236933654 @default.
- W2024854034 hasVolume "63" @default.
- W2024854034 isParatext "false" @default.
- W2024854034 isRetracted "false" @default.
- W2024854034 magId "2024854034" @default.
- W2024854034 workType "article" @default.