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- W2024861989 abstract "An expression of the structure-dependent energy of simple metal-noble metal binary alloy is given on the basis of the pseudopotential method. The energy is expressed as a sum of three parts; a band-structure energy, an electrostatic energy and a repulsive overlap energy, each of which is characterized by the usual long-range and short-range order parameters. The energy in a disordered state and the ordering energy are calculated for the AgMg, AuMg and AgAl systems, using the pseudopotential form factors and the overlap potentials of noble metals given by Moriarty. The numerical results reproduce qualitatively the observed phase diagrams; the existences of β- and ϵ-phases in the AgMg system, of β-phase in AuMg and of β- and ζ-phases in AgAl. The L20-type ordered phase (β′-phase) of AgMg alloy which remains ordered up to the melting point is well explained. Further, an estimation of the local ordering energy suggests that a clustering appears in the Al-rich region of AgAl alloy. However, the calculations fail to interpret the ordering behavior of β′-phase in the AuMg system and the short-range order of Ag-rich AgAl alloy. The role of individual terms of the structure-dependent energy on alloying is discussed." @default.
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- W2024861989 date "1974-01-01" @default.
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- W2024861989 title "Alloying behaviors of AgMg, AuMg and AgAl alloys" @default.
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- W2024861989 doi "https://doi.org/10.1016/0022-3697(74)90019-5" @default.
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