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- W2024862799 abstract "A ligand containing two 2-hydroxyphenylpyrazolyl groups around a pyridine core (H4L) reacts with Ni(II) in basic and aerobic conditions to produce a rare scalene triangular complex with formula [Ni3(L)(CO3)(H2O)(py)7] (1). This complex crystallizes in the form of pairs of molecules linked to each other through strong H-bonding interactions. The magnetic exchange interactions in this system have been studied, leading to intramolecular coupling constants J1 = −15.5 cm−1, J2 = −0.4 cm−1, J3 = −3.1 cm−1 (in agreement with the values calculated by DFT) and presumably a very unusually strong intermolecular coupling of J4 = −19.8 cm−1. All the above constants in the convention of H = −2ΣJij(SiSj) for the exchange Hamiltonian." @default.
- W2024862799 created "2016-06-24" @default.
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- W2024862799 date "2013-03-01" @default.
- W2024862799 modified "2023-10-02" @default.
- W2024862799 title "Two isosceles coordination [Ni3] triangles strongly interacting via hydrogen bonds" @default.
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- W2024862799 doi "https://doi.org/10.1016/j.poly.2012.05.027" @default.
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