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- W2024863154 abstract "Abstract A treatment is presented for the effect of intermolecular vibrational energy transfer on the diffusion coefficient of vibrationally excited molecules. An analytic treatment based on random walk statistics and a Monte Carlo type calculation have been performed. Both methods yield very similar results which correlate well with existing experimental studies. A hard sphere collision model is treated extensively with comparisons made to other internmolecular potentials. The results support the involvement of long range energy transfer in V → V interactions. The effect of temeprature on the diffusion coefficient of vibrationally excited molecules is calculated, with applications to the CO * 2 CO 2 system." @default.
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- W2024863154 title "Diffusion of vibrationally excited molecules" @default.
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- W2024863154 doi "https://doi.org/10.1016/0301-0104(76)80154-1" @default.
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