Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024884735> ?p ?o ?g. }
Showing items 1 to 81 of
81
with 100 items per page.
- W2024884735 endingPage "1254" @default.
- W2024884735 startingPage "1245" @default.
- W2024884735 abstract "Reactions of thioquinanthrene 1 with alkali metal alkanethiolates in DMSO or DMF at 70° proceeded through a stage of the S→S type of the Smiles rearrangement (3′-quinolinethiolate 2A→4′-quinolinethiolate 3A) to give 4,4′-dialkylthio-3,3′-diquinolinyl sulfides 3 as the final products. When these reactions were carried out at 20° two types of the products were isolated: 3′,4-dialkylthio-3,4′-diquinolinyl sulfides 2 or sulfides 3 depending on the reaction time (1 hour or 7 days). Under acidic conditions 3′-quinolinethiolate 2A underwent intramolecular cyclization to dithiin 1. Reactions of dithiin 1 with sodium alkanethiolates at 20°, realized as a one-pot procedure, led to various 3,4-dialkylthioquinolines 7. The rearrangement of other 3′-quinolinethiolates 8A and 11A (the products of the reactions of dithiin 1 with sodium sulfide and sodium methoxide) needed higher temperature (140°)." @default.
- W2024884735 created "2016-06-24" @default.
- W2024884735 creator A5042130869 @default.
- W2024884735 date "1995-07-01" @default.
- W2024884735 modified "2023-09-25" @default.
- W2024884735 title "Reactions of thioquinanthrene with alkanethiolates. The smiles rearrangement of diquinolinyl sulfides" @default.
- W2024884735 cites W111047642 @default.
- W2024884735 cites W1520465224 @default.
- W2024884735 cites W1520923664 @default.
- W2024884735 cites W1968111892 @default.
- W2024884735 cites W1970386314 @default.
- W2024884735 cites W1975309111 @default.
- W2024884735 cites W1984696380 @default.
- W2024884735 cites W2032032873 @default.
- W2024884735 cites W2065530099 @default.
- W2024884735 cites W2086580580 @default.
- W2024884735 cites W2152768394 @default.
- W2024884735 cites W2334281581 @default.
- W2024884735 cites W2334849620 @default.
- W2024884735 cites W2439519084 @default.
- W2024884735 cites W2473205342 @default.
- W2024884735 cites W2605482852 @default.
- W2024884735 cites W2605995536 @default.
- W2024884735 cites W4240721506 @default.
- W2024884735 cites W4246725611 @default.
- W2024884735 cites W4248997941 @default.
- W2024884735 cites W4252585652 @default.
- W2024884735 cites W4301804961 @default.
- W2024884735 doi "https://doi.org/10.1002/jhet.5570320426" @default.
- W2024884735 hasPublicationYear "1995" @default.
- W2024884735 type Work @default.
- W2024884735 sameAs 2024884735 @default.
- W2024884735 citedByCount "13" @default.
- W2024884735 countsByYear W20248847352016 @default.
- W2024884735 crossrefType "journal-article" @default.
- W2024884735 hasAuthorship W2024884735A5042130869 @default.
- W2024884735 hasConcept C155647269 @default.
- W2024884735 hasConcept C178790620 @default.
- W2024884735 hasConcept C179104552 @default.
- W2024884735 hasConcept C185592680 @default.
- W2024884735 hasConcept C198091228 @default.
- W2024884735 hasConcept C2777878547 @default.
- W2024884735 hasConcept C2779587451 @default.
- W2024884735 hasConcept C2779607525 @default.
- W2024884735 hasConcept C2780596425 @default.
- W2024884735 hasConcept C2781189857 @default.
- W2024884735 hasConcept C537181965 @default.
- W2024884735 hasConcept C75079739 @default.
- W2024884735 hasConceptScore W2024884735C155647269 @default.
- W2024884735 hasConceptScore W2024884735C178790620 @default.
- W2024884735 hasConceptScore W2024884735C179104552 @default.
- W2024884735 hasConceptScore W2024884735C185592680 @default.
- W2024884735 hasConceptScore W2024884735C198091228 @default.
- W2024884735 hasConceptScore W2024884735C2777878547 @default.
- W2024884735 hasConceptScore W2024884735C2779587451 @default.
- W2024884735 hasConceptScore W2024884735C2779607525 @default.
- W2024884735 hasConceptScore W2024884735C2780596425 @default.
- W2024884735 hasConceptScore W2024884735C2781189857 @default.
- W2024884735 hasConceptScore W2024884735C537181965 @default.
- W2024884735 hasConceptScore W2024884735C75079739 @default.
- W2024884735 hasIssue "4" @default.
- W2024884735 hasLocation W20248847351 @default.
- W2024884735 hasOpenAccess W2024884735 @default.
- W2024884735 hasPrimaryLocation W20248847351 @default.
- W2024884735 hasRelatedWork W1988618997 @default.
- W2024884735 hasRelatedWork W2002269779 @default.
- W2024884735 hasRelatedWork W2024884735 @default.
- W2024884735 hasRelatedWork W2082703485 @default.
- W2024884735 hasRelatedWork W2169713560 @default.
- W2024884735 hasRelatedWork W2223969170 @default.
- W2024884735 hasRelatedWork W2391851651 @default.
- W2024884735 hasRelatedWork W2949486610 @default.
- W2024884735 hasRelatedWork W2953120811 @default.
- W2024884735 hasRelatedWork W2998619417 @default.
- W2024884735 hasVolume "32" @default.
- W2024884735 isParatext "false" @default.
- W2024884735 isRetracted "false" @default.
- W2024884735 magId "2024884735" @default.
- W2024884735 workType "article" @default.