FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024888275> ?p ?o ?g. }

• W2024888275 endingPage "102" @default.
• W2024888275 startingPage "99" @default.
• W2024888275 abstract "In this work, a series of Pd catalysts supported on commercially available activated carbon (Norit ®) were prepared by employing different metal precursors (Pd(NO3)2 and Na2PdCl4) by the impregnation-reduction method at different pH. Catalysts were tested for the liquid phase decomposition of formic acid to generate hydrogen. The best results, in terms of small particle size and high catalytic activity were achieved for the Pd/C sample prepared by using Pd(NO3)2 salt impregnated at pH = 2.5, and reduced with sodium borohydride. The particle size of the best Pd/C catalyst is (4.1 ± 1.4) nm with initial TOFs of 2929 and 683 h−1 at 60 and 30 °C respectively and an apparent activation energy of 40 kJ mol−1. Samples prepared by using Na2PdCl4 precursor, consisted of particles with higher size and thus lower activity than the ones prepared with Pd(NO3)2. Regardless the Pd precursor employed, the best results in terms of particle size and activity were achieved at the point of zero charge of the support when the Pd species and the carbon surface were both neutral. The impregnation pH not only determines the particle size, but also the nature of the reducing agent does. The catalytic activity was shown to be size-dependent and it was shown that a mixture of surface Pd0 and PdII oxidation states is beneficial for the activity. When comparing with literature catalysts with similar composition, we found that our best catalyst is competitive enough and that Norit ® support could be promising for future studies on this reaction." @default.
• W2024888275 created "2016-06-24" @default.
• W2024888275 creator A5050600755 @default.
• W2024888275 date "1983-01-01" @default.
• W2024888275 modified "2023-10-14" @default.
• W2024888275 title "Sensitivity factors for XPS analysis of surface atoms" @default.
• W2024888275 cites W1974426736 @default.
• W2024888275 cites W1988552001 @default.
• W2024888275 cites W2000366249 @default.
• W2024888275 cites W2004239068 @default.
• W2024888275 cites W2040543325 @default.
• W2024888275 cites W2041881489 @default.
• W2024888275 cites W2042161369 @default.
• W2024888275 cites W2046152022 @default.
• W2024888275 cites W2067366639 @default.
• W2024888275 cites W2071801141 @default.
• W2024888275 cites W2102842594 @default.
• W2024888275 doi "https://doi.org/10.1016/0368-2048(83)85087-7" @default.
• W2024888275 hasPublicationYear "1983" @default.
• W2024888275 type Work @default.
• W2024888275 sameAs 2024888275 @default.
• W2024888275 citedByCount "210" @default.
• W2024888275 countsByYear W20248882752012 @default.
• W2024888275 countsByYear W20248882752013 @default.
• W2024888275 countsByYear W20248882752014 @default.
• W2024888275 countsByYear W20248882752015 @default.
• W2024888275 countsByYear W20248882752016 @default.
• W2024888275 countsByYear W20248882752017 @default.
• W2024888275 countsByYear W20248882752018 @default.
• W2024888275 countsByYear W20248882752019 @default.
• W2024888275 countsByYear W20248882752020 @default.
• W2024888275 countsByYear W20248882752021 @default.
• W2024888275 countsByYear W20248882752022 @default.
• W2024888275 countsByYear W20248882752023 @default.
• W2024888275 crossrefType "journal-article" @default.
• W2024888275 hasAuthorship W2024888275A5050600755 @default.
• W2024888275 hasConcept C104779481 @default.
• W2024888275 hasConcept C111368507 @default.
• W2024888275 hasConcept C124681953 @default.
• W2024888275 hasConcept C127313418 @default.
• W2024888275 hasConcept C127413603 @default.
• W2024888275 hasConcept C13965031 @default.
• W2024888275 hasConcept C140205800 @default.
• W2024888275 hasConcept C147789679 @default.
• W2024888275 hasConcept C150394285 @default.
• W2024888275 hasConcept C159985019 @default.
• W2024888275 hasConcept C161790260 @default.
• W2024888275 hasConcept C175708663 @default.
• W2024888275 hasConcept C178790620 @default.
• W2024888275 hasConcept C179104552 @default.
• W2024888275 hasConcept C185592680 @default.
• W2024888275 hasConcept C187530423 @default.
• W2024888275 hasConcept C192562407 @default.
• W2024888275 hasConcept C2777379063 @default.
• W2024888275 hasConcept C2778517922 @default.
• W2024888275 hasConcept C2778931688 @default.
• W2024888275 hasConcept C2779647737 @default.
• W2024888275 hasConcept C2780048404 @default.
• W2024888275 hasConcept C42360764 @default.
• W2024888275 hasConcept C502130503 @default.
• W2024888275 hasConcept C512968161 @default.
• W2024888275 hasConcept C544153396 @default.
• W2024888275 hasConceptScore W2024888275C104779481 @default.
• W2024888275 hasConceptScore W2024888275C111368507 @default.
• W2024888275 hasConceptScore W2024888275C124681953 @default.
• W2024888275 hasConceptScore W2024888275C127313418 @default.
• W2024888275 hasConceptScore W2024888275C127413603 @default.
• W2024888275 hasConceptScore W2024888275C13965031 @default.
• W2024888275 hasConceptScore W2024888275C140205800 @default.
• W2024888275 hasConceptScore W2024888275C147789679 @default.
• W2024888275 hasConceptScore W2024888275C150394285 @default.
• W2024888275 hasConceptScore W2024888275C159985019 @default.
• W2024888275 hasConceptScore W2024888275C161790260 @default.
• W2024888275 hasConceptScore W2024888275C175708663 @default.
• W2024888275 hasConceptScore W2024888275C178790620 @default.
• W2024888275 hasConceptScore W2024888275C179104552 @default.
• W2024888275 hasConceptScore W2024888275C185592680 @default.
• W2024888275 hasConceptScore W2024888275C187530423 @default.
• W2024888275 hasConceptScore W2024888275C192562407 @default.
• W2024888275 hasConceptScore W2024888275C2777379063 @default.
• W2024888275 hasConceptScore W2024888275C2778517922 @default.
• W2024888275 hasConceptScore W2024888275C2778931688 @default.
• W2024888275 hasConceptScore W2024888275C2779647737 @default.
• W2024888275 hasConceptScore W2024888275C2780048404 @default.
• W2024888275 hasConceptScore W2024888275C42360764 @default.
• W2024888275 hasConceptScore W2024888275C502130503 @default.
• W2024888275 hasConceptScore W2024888275C512968161 @default.
• W2024888275 hasConceptScore W2024888275C544153396 @default.
• W2024888275 hasIssue "2" @default.
• W2024888275 hasLocation W20248882751 @default.
• W2024888275 hasOpenAccess W2024888275 @default.
• W2024888275 hasPrimaryLocation W20248882751 @default.
• W2024888275 hasRelatedWork W1971095641 @default.
• W2024888275 hasRelatedWork W1975659229 @default.
• W2024888275 hasRelatedWork W2006685724 @default.
• W2024888275 hasRelatedWork W2065466533 @default.
• W2024888275 hasRelatedWork W2093076978 @default.
• W2024888275 hasRelatedWork W2098118617 @default.

• next