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- W2024889575 abstract "Abstract The Raman vibrational spectra of 1,2-dichlorotetramethyldisilane recorded at various temperatures prove that two rotamers, gauche and anti, are present in the liquid state due to restricted rotation of the SiMe2Cl groups. The solid is composed of the anti rotamer exclusively. From a van’t Hoff plot, the enthalpy difference ΔH=Hgauche−Hanti has been determined as 1.01±0.2 kJ mol−1, the anti rotamer being more stable. Ab initio SCF-HF calculations of equilibrium geometries, harmonic vibrations and harmonic force fields have been performed for both rotamers and the vibrational spectra have been assigned employing these results." @default.
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- W2024889575 date "1999-11-01" @default.
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- W2024889575 title "Rotational isomerism of 1,2-dichlorotetramethyldisilane studied by Raman spectroscopy and ab initio quantum chemical calculations" @default.
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- W2024889575 doi "https://doi.org/10.1016/s1386-1425(99)00055-4" @default.
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