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- W2024892359 endingPage "903" @default.
- W2024892359 startingPage "893" @default.
- W2024892359 abstract "A class of bifunctionalized phosphine complexes bearing a stereogenic center at phosphorus have been synthesized through stepwise insertion and hydration of the two alkynyl groups of a prochiral dialkynylphosphine complex, [Ru(η6-benzene){PPh(C≡CCH3)2}Cl2]. One of the two alkyne moieties of this complex inserted into the Pd−C bond of cyclopalladated benzylamine complexes to yield bimetallic complexes containing two stereogenic centers at ruthenium and phosphorus with high stereoselectivity and yield. Subsequently, the remaining free alkynyl group underwent hydration in a mixed solvent system of DCM/acetone/H2O (2:10:1), which resulted in the formation of bimetallic zwitterions bearing anionic palladium(II) and cationic ruthenium(II) centers. The carbon−carbon triple bond was converted into a ketonyl group during the hydration, and the absolute configuration at phosphorus was observed to remain unchanged in the products. All structures of the insertion and hydration products have been identified by X-ray analyses or 2D ROESY NMR studies." @default.
- W2024892359 created "2016-06-24" @default.
- W2024892359 creator A5017011714 @default.
- W2024892359 creator A5034309937 @default.
- W2024892359 creator A5053217432 @default.
- W2024892359 creator A5054562744 @default.
- W2024892359 creator A5073696111 @default.
- W2024892359 date "2010-01-15" @default.
- W2024892359 modified "2023-09-23" @default.
- W2024892359 title "Syntheses of Bimetallic Zwitterionic Complexes Containing Stereogenic Bifunctionalized Phosphine through Stepwise Insertion and Hydration Reactions" @default.
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