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- W2024933050 abstract "The electrodeposition of iron and Zn-Fe alloys on polycrystalline nickel was investigated in the 40.0-60.0 mol % zinc chloride-1-ethyl-3-methylimidazolium chloride ionic liquid containing iron(II) at 90°C. Iron(II) was electrochemically reduced to iron metal before the reduction of zinc(II) to zinc metal, and anomalous codeposition of Zn-Fe did not occur in this ionic liquid. Underpotential deposition of zinc on iron was observed prior to the electrodeposition of bulk zinc. Dimensionless chronoamperometric current/time transients for the underpotential deposition of zinc on iron were in good accord with the theoretical transients for the two-dimensional nucleation and/or growth of the nuclei. Zn-Fe alloys could be prepared in the potential range of the underpotential of zinc on iron or the potential range where bulk deposition of zinc occurred. Energy-dispersive spectroscopy data indicated that the composition of the Zn-Fe alloys was dependent upon the deposition potential and the iron(II) concentration in the plating solution. The morphologies of the Zn-Fe codeposits were examined by scanning electron microscopy. © 2003 The Electrochemical Society. All rights reserved." @default.
- W2024933050 created "2016-06-24" @default.
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- W2024933050 date "2004-01-01" @default.
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- W2024933050 title "Nonanomalous Electrodeposition of Zinc-Iron Alloys in an Acidic Zinc Chloride-1-ethyl-3-methylimidazolium Chloride Ionic Liquid" @default.
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- W2024933050 doi "https://doi.org/10.1149/1.1628235" @default.
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