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• W2024938666 abstract "Four diiron dithiolate complexes containing ortho-acylamino-functionalized arenethiolato ligands, [(μ-S-2-RCONHC6H4)2Fe2(CO)6] (R = CH3, 1; CF3, 2; C6H5, 3; 4-FC6H4, 4), were synthesized and well characterized as biomimetic models of the Fe–Fe hydrogenase active site. The molecular structures of 3 and 4 were determined by X-ray crystallography. The intra-ligand NH⋯S hydrogen bonds were studied by the X-ray analysis and by the 1H NMR spectroscopy. The contribution of the NH⋯S hydrogen bonds to the reduction potentials of complexes 1–4 was investigated by electrochemistry. The first reduction potentials of complexes 1–4 exhibit large positive shifts, that is, 220–320 mV in comparison to that of the analogous complex [(μ-SPh)2Fe2(CO)6] and 370–470 mV to that of [(μ-pdt)2Fe2(CO)6] (pdt = propane-1,3-dithiolato). Complex 4 is capable of electrocatalysing proton reduction of acetic acid at relatively low overpotential (ca. 0.2 V) in acetonitrile." @default.
• W2024938666 created "2016-06-24" @default.
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• W2024938666 date "2008-01-01" @default.
• W2024938666 modified "2023-10-03" @default.
• W2024938666 title "Diiron dithiolate complexes containing intra-ligand NH⋯S hydrogen bonds: [FeFe] hydrogenase active site models for the electrochemical proton reduction of HOAc with low overpotential" @default.
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• W2024938666 doi "https://doi.org/10.1039/b715990k" @default.
• W2024938666 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18461194" @default.
• W2024938666 hasPublicationYear "2008" @default.
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