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• W2024943357 abstract "The reaction of the pyridyne-2-carboxylate acid with CuBr2 leads to the formation of the compound of the formula [Cu(2-pic)2Br2][(2-picH)2], where 2-pic is pyridyne-2-carboxylate ion and 2-picH is cation of the pyridyne-2-carboxylate ion with deprotonated carboxyl oxygen and protonated pyridyl nitrogen atoms. The compound was characterized by infrared, ligand field and EPR spectroscopy and magnetic properties and also the single-crystal structure was determined. The structure of [Cu(2-pic)2Br2]2− anion shows a strongly tetragonally distorted octahedral stereochemistry (CuN2O2Br2 chromophore), resulting from the bidentate N,O-bonded two chelate ligands and two bromide ions in an axial position." @default.
• W2024943357 created "2016-06-24" @default.
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• W2024943357 date "2008-04-01" @default.
• W2024943357 modified "2023-09-23" @default.
• W2024943357 title "Synthesis, characterization and crystal structure of [Cu(2-pic)2Br2][(2-picH)2]" @default.
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• W2024943357 doi "https://doi.org/10.1016/j.molstruc.2007.07.015" @default.
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