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- W2024951617 abstract "Five polyallyl ester monomers that contain aromatic imide groups were synthesized as thermally stable laminating resins. From these monomers soluble and low-melting prepolymers were obtained by radical polymerization in aprotic polar solvents such as N,N-dimethylacetamide, N,N-dimethylformamide, or N-methyl -2-pyrrolidone. The prepolymers are oligomeric compounds in which DP = 3–6 and have lower melting points than the corresponding monomers. It is assumed that the reaction of solvent molecule participates in the polymerization. Whereas, the bulk and the solution polymerization in n-butyl acetate or n-propyl alcohol yielded insoluble and infusible polymer. The relatively low-melting prepolymers were curable at 150–180°C without the evolution of volatile by-products. Resulting glass-fiber laminates have no glass transition point below 300°C and thermooxidative stability at 330°C." @default.
- W2024951617 created "2016-06-24" @default.
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- W2024951617 date "1979-08-01" @default.
- W2024951617 modified "2023-09-26" @default.
- W2024951617 title "Soluble and curable prepolymers from polyallyl ester monomers containing aromatic imide groups" @default.
- W2024951617 doi "https://doi.org/10.1002/pol.1979.170170808" @default.
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