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- W2024951650 abstract "A barrelene derivative fragments to afford benzene and trappable 1,2,3-tricyanocyclopropene. The barrelene anion fragments more easily to liberate benzene and the 1,2,3-tricyanocyclopropenyl anion, which is not trappable or stable in solution. However, the major thermal product from the barrelene anion is a rearranged allyl anion that is formed by disrotatory cleavage of the cyclopropyl ring, a formally Woodward−Hoffmann-forbidden process. Several proposals are offered to rationalize this forbidden rearrangement." @default.
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- W2024951650 date "2003-08-20" @default.
- W2024951650 modified "2023-09-26" @default.
- W2024951650 title "A Forbidden Rearrangement" @default.
- W2024951650 cites W1984993108 @default.
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- W2024951650 doi "https://doi.org/10.1021/ol034997x" @default.
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