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• W2024955360 abstract "Head-head coupling of a dimethylfulvene ligand occures in the reaction of 6,6-dimethylpentafulvene (1a) with [(C5H5)Co(C2H4)2] (7) to give (1,1,2,2-tetramethyl-1,2-ethanediyl)bis(cobaltocene) (8a). In contrast, the mononuclear η4-fulvene complexes 3b, c are obtained from 6-ethyl-6-methyl-(1b) and 6,6-diethylfulvene (1c) and 7. The crystal structures of 8a and the corresponding bis(ferrocene) 9a have been determined. The electrochemical behaviour of 8a and 9a shows 8a+, 8a−, and 9a+ to be localised mixed-valence species. Molecular mechanics calculations have been performed on the title complex and related derivatives." @default.
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• W2024955360 date "1995-03-01" @default.
• W2024955360 modified "2023-10-12" @default.
• W2024955360 title "(C ₅ H ₅ )Co‐Induced Head‐Head Coupling of Dimethylfulvene: Formation, Molecular Structure and Electrochemistry of (1,1,2,2‐Tetramethyl‐1,2‐ethanediyl)bis(cobaltocene)" @default.
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• W2024955360 doi "https://doi.org/10.1002/cber.19951280317" @default.
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