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• W2024961918 abstract "The rate of polymerization of acrylonitrile, using the Ce(IV)–cyclohexanone redox system as an initiator, was studied kinetically, in the presence of 0.015M sodium dodecyl sulfate (SDS), over a temperature range of 25–45°C. The rate of polymerization (RP), percentage of monomer conversion, and rate of Ce(IV) consumption (−RCe) were found to increase with the concentration of SDS, above its CMC. The effect of [AN], [Ce(IV)], [H+], and the ionic strength were also studied. The overall activation energies for the polymerization processes were computed to be 23.14 and 17.64 kcal/mol in the absence and presence of 0.015M SDS. A suitable kinetic mechanistic scheme for the free-radical mechanism was proposed. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2066–2072, 2003" @default.
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• W2024961918 date "2003-01-01" @default.
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• W2024961918 title "Acrylonitrile polymerization initiated by Ce(IV)-cyclohexanone redox system in presence of surfactant" @default.
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• W2024961918 doi "https://doi.org/10.1002/app.12810" @default.
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