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• W2024974312 abstract "The electrical conductivity σAC and the thermoelectric power α for the MoO3-MoO3−n-MoO2 system, namely MoO3, Mo13O38, Mo9O26, Mo8O23, Mo17O47, Mo4O11 and MoO2, are measured over a wide temperature range. The conductivity value at room temperature is found to increase with departure from stoichiometry. MoO3 and its suboxides exhibit semiconducting behaviour while MoO2 at low temperature exhibits semimetal-like character of 10−2 Ω−1 cm−1 rather than a semiconducting one. Above room temperature MoO2 gave a ΔE value of 0.85 eV, indicating that this metal-like conduction is not taking place. Some discontinuities are present in the log σ vs. 1/T curves for all samples. These are confirmed by DTA. The thermoelectric power indicates that all oxides are n-types semiconductors up to 300°C. The value at room temperature decreases with departure from stoichiometry. The most pronounced change of both σ and α is at Mo8O23, i.e. at x=0.125." @default.
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• W2024974312 date "1982-04-01" @default.
• W2024974312 modified "2023-10-17" @default.
• W2024974312 title "Transport properties of molybdenum trioxide and its suboxides" @default.
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• W2024974312 doi "https://doi.org/10.1016/0040-6031(82)85062-4" @default.
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