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• W2024982207 abstract "The unprecedented self-assembled formation of a two-dimensional salicylaldimine lanthanum coordination polymer is proved by the X-ray diffraction analysis of new lanthanum(III) nitrate complex containing the N,N′-bis(salicylidene)-1,4-butanediamine ligand L, which was prepared in situ through one-step template [2+1] Schiff base condensation of salicylaldehyde with 1,4-butanediamine in the presence of lanthanum(III) nitrate ion and characterized by spectroscopic (IR, ESI-MS, UV–Vis, and 1H NMR) data and microanalysis. The complex displays an infinite [La2L4(NO3)6]∞ polymeric structure based on networks of ten-coordinated La(III) nodes linked by bridging L ligands. The coordination geometry around the lanthanum is a distorted bicapped dodecahedron. This polymer can be described as composed from the columns of dimers connected into chains, via the flexible chain parts of ligands." @default.
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• W2024982207 date "2007-02-01" @default.
• W2024982207 modified "2023-10-17" @default.
• W2024982207 title "Self-assembled two-dimensional salicylaldimine lanthanum(III) nitrate coordination polymer" @default.
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• W2024982207 doi "https://doi.org/10.1016/j.ica.2006.07.071" @default.
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