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- W2024982876 abstract "Various mixtures of phenolic compounds, most of them being priority pollutant phenols, are separated by coelectroosmotic capillary electrophoresis. To obtain short separation times a codirectional movement of the anionic phenolates and the electroosmotic flow (EOF) is established by adding a polycationic EOF modifier to the alkaline buffer electrolyte. To increase the selectivity of the separation and the resolution between the solutes, organic solvent mixtures are added to the separation buffer. Furthermore, coelectroosmotic MECC of phenols using cetyltrimethylammonium bromide (CTAB) as pseudo-stationary phase and acetonitrile as organic modifier is performed. The developed methods are used for the fast separation of the 9 cresol and xylenol isomers, as well as mixtures of 18 chlorophenols, 11 phenols (acid extractable mixture, EPA M-625A), and 9 phenols (EPA M-8040B-R). Separation mechanisms are discussed on the basis of solvation effects of the phenolic solutes. In the case of CTAB-MECC the influence of the CTAB concentration and of acetonitrile on the solubilization of the phenols is investigated." @default.
- W2024982876 created "2016-06-24" @default.
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- W2024982876 date "1997-08-01" @default.
- W2024982876 modified "2023-09-24" @default.
- W2024982876 title "Separation of Priority Pollutant Phenols with Coelectroosmotic Capillary Electrophoresis" @default.
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- W2024982876 doi "https://doi.org/10.1021/ac9703717" @default.
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