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• W2024989118 startingPage "173" @default.
• W2024989118 abstract "Crosslinked polystyrene resins containing pendant benzyl acrylate or chiral acrylates derived from R-(−)-1,3-butanedoil reacted with 1,3-butadiene or 2,3-dimethyl-1,3-butadiene in the presence of the Lewis acid catalysts TiCl4, TiCl3(OiPr), or TiCl2(OiPr)2 to yield Diels-Alder adducts. Cleavage of the adducts gave racemic or optically active 3-cyclohexen-1-ylmethanol and 3,4-dimethyl-3-cyclohexen-1-ylmethanol. The polymerbound Diels-Alder reactions were compared with their analogous reactions in solution. In reactions leading to optically active products the enantiomeric excesses on the polymer were at least as high as those performed in solution." @default.
• W2024989118 created "2016-06-24" @default.
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• W2024989118 date "1988-04-01" @default.
• W2024989118 modified "2023-09-23" @default.
• W2024989118 title "Asymmetric induction in the cycloaddition of 1,3-butadiene to a polymer-bound chiral acrylate" @default.
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• W2024989118 doi "https://doi.org/10.1016/0167-6989(88)90239-5" @default.
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