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- W2024997752 abstract "The first aliphatic bis(chlorovinylidene cyanide) monomer, 1,3-bis(1-chloro-2,2-dicyanovinyl)adamantane, has been synthesized and polymerized with appropriate diamines to give adamantane-containing aromatic-aliphatic and all aliphatic poly(enaminonitriles) (PEANs) via vinylic nucleophilic substitution polymerization. The PEANs showed excellent solubility in polar aprotic solvents and good thermal stability (10% weight loss in air > 320 °C), despite the aliphatic contents of the polymers. Solution inherent viscosities of 0.23–0.90 dL/g were obtained. Three other new PEANs containing the adamantane-based cardo group were also synthesized via vinylic nucleophilic substitution polymerization from the adamanaine-containing cardo diamine 2,2-bis[4-(4-aminophenoxy)phenyl]adamantane. The cardo PEANs showed better solubility in common organic solvents than the corresponding cardo polyamides. They also showed good thermal stabilities (10% weight loss in air > 339 °C) comparable to those of the corresponding cardo polyamides." @default.
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- W2024997752 date "2009-06-01" @default.
- W2024997752 modified "2023-10-18" @default.
- W2024997752 title "Synthesis and characterization of adamantane-containing poly(enaminonitriles)" @default.
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- W2024997752 doi "https://doi.org/10.1016/j.polymer.2009.04.014" @default.
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