Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024998729> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W2024998729 endingPage "2350" @default.
- W2024998729 startingPage "2339" @default.
- W2024998729 abstract "The effect of reaction conditions on the extent of conversion in hydrolysis of blackcurrant oil was investigated. The enzyme used was Lipozyme, a lipase from Mucor miehei immobilised on macroporous anionic resin. The reaction was carried out in a continuous flow reactor at 10–28MPa and 30–50°C with carbon dioxide saturated with oil and water (55–100%) flowing up through the enzyme bed. Analysis of product composition indicated unfavourable hydrodynamics with significant mixing in the reactor when solvent interstitial velocity was lower than 4cmmin−1, while above this velocity value the flow pattern was near to plug flow. Lipase stability was very good with no activity reduction observed during a long-term experiment. The reaction rate was a function of the ratio of enzyme load to solvent volumetric flow rate. A complete hydrolysis of oil was achieved in the experiments carried out with the enzyme load of 0.8g and CO2 flow rate of 0.4–0.9gmin−1. The effects of pressure (10–25MPa) and temperature (30–40°C) on the reaction rate were small, and the effects of CO2 saturation with water and of enzyme distribution in the reactor were negligible. Lipozyme displayed specificity towards linolenic acids; the release of α-linolenic acid was faster and that of γ-linolenic acid slower than the release of other constituent acids present in blackcurrant oil." @default.
- W2024998729 created "2016-06-24" @default.
- W2024998729 creator A5002827393 @default.
- W2024998729 creator A5065085743 @default.
- W2024998729 date "2003-06-01" @default.
- W2024998729 modified "2023-10-01" @default.
- W2024998729 title "Lipase-catalysed hydrolysis of blackcurrant oil in supercritical carbon dioxide" @default.
- W2024998729 cites W1969498746 @default.
- W2024998729 cites W1976614658 @default.
- W2024998729 cites W1980924056 @default.
- W2024998729 cites W1987616939 @default.
- W2024998729 cites W1999335789 @default.
- W2024998729 cites W2006276763 @default.
- W2024998729 cites W2008627782 @default.
- W2024998729 cites W2033158608 @default.
- W2024998729 cites W2053495765 @default.
- W2024998729 cites W2057341043 @default.
- W2024998729 cites W2062917105 @default.
- W2024998729 cites W2068728652 @default.
- W2024998729 cites W2069247186 @default.
- W2024998729 cites W2077605666 @default.
- W2024998729 cites W2088989994 @default.
- W2024998729 cites W2090914258 @default.
- W2024998729 cites W2318443532 @default.
- W2024998729 cites W2334635040 @default.
- W2024998729 cites W4251765596 @default.
- W2024998729 doi "https://doi.org/10.1016/s0009-2509(03)00064-2" @default.
- W2024998729 hasPublicationYear "2003" @default.
- W2024998729 type Work @default.
- W2024998729 sameAs 2024998729 @default.
- W2024998729 citedByCount "36" @default.
- W2024998729 countsByYear W20249987292013 @default.
- W2024998729 countsByYear W20249987292014 @default.
- W2024998729 countsByYear W20249987292015 @default.
- W2024998729 countsByYear W20249987292017 @default.
- W2024998729 countsByYear W20249987292018 @default.
- W2024998729 countsByYear W20249987292020 @default.
- W2024998729 countsByYear W20249987292021 @default.
- W2024998729 countsByYear W20249987292022 @default.
- W2024998729 countsByYear W20249987292023 @default.
- W2024998729 crossrefType "journal-article" @default.
- W2024998729 hasAuthorship W2024998729A5002827393 @default.
- W2024998729 hasAuthorship W2024998729A5065085743 @default.
- W2024998729 hasConcept C118419359 @default.
- W2024998729 hasConcept C134458231 @default.
- W2024998729 hasConcept C147789679 @default.
- W2024998729 hasConcept C161790260 @default.
- W2024998729 hasConcept C175113610 @default.
- W2024998729 hasConcept C178790620 @default.
- W2024998729 hasConcept C181199279 @default.
- W2024998729 hasConcept C185592680 @default.
- W2024998729 hasConcept C2779697368 @default.
- W2024998729 hasConcept C2780471494 @default.
- W2024998729 hasConcept C43617362 @default.
- W2024998729 hasConcept C47502133 @default.
- W2024998729 hasConcept C530467964 @default.
- W2024998729 hasConcept C67334161 @default.
- W2024998729 hasConcept C94412978 @default.
- W2024998729 hasConceptScore W2024998729C118419359 @default.
- W2024998729 hasConceptScore W2024998729C134458231 @default.
- W2024998729 hasConceptScore W2024998729C147789679 @default.
- W2024998729 hasConceptScore W2024998729C161790260 @default.
- W2024998729 hasConceptScore W2024998729C175113610 @default.
- W2024998729 hasConceptScore W2024998729C178790620 @default.
- W2024998729 hasConceptScore W2024998729C181199279 @default.
- W2024998729 hasConceptScore W2024998729C185592680 @default.
- W2024998729 hasConceptScore W2024998729C2779697368 @default.
- W2024998729 hasConceptScore W2024998729C2780471494 @default.
- W2024998729 hasConceptScore W2024998729C43617362 @default.
- W2024998729 hasConceptScore W2024998729C47502133 @default.
- W2024998729 hasConceptScore W2024998729C530467964 @default.
- W2024998729 hasConceptScore W2024998729C67334161 @default.
- W2024998729 hasConceptScore W2024998729C94412978 @default.
- W2024998729 hasIssue "11" @default.
- W2024998729 hasLocation W20249987291 @default.
- W2024998729 hasOpenAccess W2024998729 @default.
- W2024998729 hasPrimaryLocation W20249987291 @default.
- W2024998729 hasRelatedWork W1963653379 @default.
- W2024998729 hasRelatedWork W1966928397 @default.
- W2024998729 hasRelatedWork W1993866658 @default.
- W2024998729 hasRelatedWork W2003173719 @default.
- W2024998729 hasRelatedWork W2042179653 @default.
- W2024998729 hasRelatedWork W2097112371 @default.
- W2024998729 hasRelatedWork W2353062224 @default.
- W2024998729 hasRelatedWork W2752606711 @default.
- W2024998729 hasRelatedWork W3099705382 @default.
- W2024998729 hasRelatedWork W36593232 @default.
- W2024998729 hasVolume "58" @default.
- W2024998729 isParatext "false" @default.
- W2024998729 isRetracted "false" @default.
- W2024998729 magId "2024998729" @default.
- W2024998729 workType "article" @default.