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- W2024999768 abstract "Copper-catalyzed asymmetric sulfoxidation of aryl benzyl and aryl alkyl sulfides, using aqueous hydrogen peroxide as the oxidant, has been investigated. A relationship between the steric effects of the sulfide substituents and the enantioselectivity of the oxidation has been observed, with up to 93% ee for 2-naphthylmethyl phenyl sulfoxide, in modest yield in this instance (up to 30%). The influence of variation of solvent and ligand structure was examined, and the optimized conditions were then used to oxidize a number of aryl alkyl and aryl benzyl sulfides, producing sulfoxides in excellent yields in most cases (up to 92%), and good enantiopurities in certain cases (up to 84% ee)." @default.
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- W2024999768 date "2012-03-12" @default.
- W2024999768 modified "2023-10-11" @default.
- W2024999768 title "Copper-Catalyzed Asymmetric Oxidation of Sulfides" @default.
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- W2024999768 doi "https://doi.org/10.1021/jo2026178" @default.
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