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- W2025056416 abstract "Organofluorine compounds have had a marked impact on medical and organochemical fields and the number of applications continues to grow. [1] These significant contributions arise from the unique changes that occur in the physical and chemical properties of ordinary organic compounds due to the presence of a fluorine-containing group. The use of Deoxo-FluorTM [N(MeOCH2CH2)2SF3] as a nucleophilic fluorinating reagent is gaining popularity. [2] Compared with DAST (Et2NSF3), the traditional deoxofluorinating agent, Deoxo-FluorTM is thermally less instable and thus more amenable to large-scale use. So far, it has been predominantly applied to convert alcohols, [3-5] aldehydes, ketones, [3a,6] glyoxalates [8] and carboxylic acids [9] into the corresponding monofluoromethyl and difluoromethylene derivatives. Also, conversion of thiocarbonyl derivatives to fluorinated products has been achieved. [7] In addition to its role as fluorinating reagent, Deoxo-FluorTM played an important role in inducing cyclizations of β-hydroxy amides (thioamides) to corresponding oxazolines (thiazolines). [10]" @default.
- W2025056416 created "2016-06-24" @default.
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- W2025056416 date "2006-09-01" @default.
- W2025056416 modified "2023-09-24" @default.
- W2025056416 title "Deoxo-Fluor [Bis(2-methoxyethyl)aminosulfur Trifluoride]: An Advanced Nucleophilic Fluorinating Reagent in Organic Synthesis" @default.
- W2025056416 doi "https://doi.org/10.1055/s-2006-950419" @default.
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